Methylene blue applied to N95 respirators and medical masks for SARS-CoV-2 decontamination: What is the likelihood of inhaling methylene blue?

COVID-19 Coronavirus Global health Personal protective equipment (PPE) Photodynamic therapy Singlet oxygen

Journal

American journal of infection control
ISSN: 1527-3296
Titre abrégé: Am J Infect Control
Pays: United States
ID NLM: 8004854

Informations de publication

Date de publication:
08 2022
Historique:
received: 15 01 2022
revised: 03 03 2022
accepted: 04 03 2022
entrez: 31 7 2022
pubmed: 1 8 2022
medline: 3 8 2022
Statut: ppublish

Résumé

Global shortage of personal protective equipment (PPE), as consequence of the COVID-19 global pandemic, has unmasked significant resource inequities prompting efforts to develop methods for safe PPE decontamination for reuse. The World Health Organization (WHO) in their Rational Use of PPE bulletin cited the use of a photodynamic dye, methylene blue, and light exposure as a viable option for N95 respirator decontamination. Because WHO noted that methylene blue (MB) would be applied to surfaces through which health care workers breathe, we hypothesized that little to no MB will be detectable by spectroscopy when the PPE is subjected to MB at supraphysiologic airflow rates. A panel of N95 respirators, medical masks, and cloth masks were sprayed with 5 cycles of 1,000 uM MB solution. Mask coupons were subjected to the equivalent of 120 L/min of 100% humidified air flow. Effluent gas was trapped in an aqueous solution and the resultant fluid was sampled for MB absorbance with a level of detection of 0.004 mg/m3. No detectable MB was identified for any mask using Ultraviolet-Visible spectroscopy. At 500-fold the amount of MB applied to N95 respirators and medical masks as were used for the decontamination study cited in the WHO Rational Use of PPE bulletin, no detectable MB was observed, thus providing safety evidence for the use of methylene blue and light exposure for mask decontamination.

Sections du résumé

BACKGROUND
Global shortage of personal protective equipment (PPE), as consequence of the COVID-19 global pandemic, has unmasked significant resource inequities prompting efforts to develop methods for safe PPE decontamination for reuse. The World Health Organization (WHO) in their Rational Use of PPE bulletin cited the use of a photodynamic dye, methylene blue, and light exposure as a viable option for N95 respirator decontamination. Because WHO noted that methylene blue (MB) would be applied to surfaces through which health care workers breathe, we hypothesized that little to no MB will be detectable by spectroscopy when the PPE is subjected to MB at supraphysiologic airflow rates.
METHODS
A panel of N95 respirators, medical masks, and cloth masks were sprayed with 5 cycles of 1,000 uM MB solution. Mask coupons were subjected to the equivalent of 120 L/min of 100% humidified air flow. Effluent gas was trapped in an aqueous solution and the resultant fluid was sampled for MB absorbance with a level of detection of 0.004 mg/m3.
RESULTS
No detectable MB was identified for any mask using Ultraviolet-Visible spectroscopy.
CONCLUSIONS
At 500-fold the amount of MB applied to N95 respirators and medical masks as were used for the decontamination study cited in the WHO Rational Use of PPE bulletin, no detectable MB was observed, thus providing safety evidence for the use of methylene blue and light exposure for mask decontamination.

Identifiants

pubmed: 35908823
pii: S0196-6553(22)00144-4
doi: 10.1016/j.ajic.2022.03.003
pmc: PMC9436551
pii:
doi:

Substances chimiques

Methylene Blue T42P99266K

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

857-862

Informations de copyright

Copyright © 2022 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Elsevier Inc. All rights reserved.

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Auteurs

Thomas S Lendvay (TS)

Department of Urology, University of Washington, Seattle Children's Hospital, Seattle, WA. Electronic address: thomas.lendvay@seattlechildrens.org.

Jinwei Xu (J)

Department of Materials Science and Engineering, Stanford University, Stanford, CA.

James Chen (J)

Department of Urology, University of Washington, Seattle, WA.

Tanner Clark (T)

Department of Radiology, University of Washington, Seattle, WA.

Yi Cui (Y)

Department of Materials Science and Engineering, Stanford University, Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, CA.

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Classifications MeSH