Resistance to the isocitrate dehydrogenase 1 mutant inhibitor ivosidenib can be overcome by alternative dimer-interface binding inhibitors.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
15 08 2022
Historique:
received: 11 04 2022
accepted: 25 07 2022
entrez: 15 8 2022
pubmed: 16 8 2022
medline: 18 8 2022
Statut: epublish

Résumé

Ivosidenib, an inhibitor of isocitrate dehydrogenase 1 (IDH1) R132C and R132H variants, is approved for the treatment of acute myeloid leukaemia (AML). Resistance to ivosidenib due to a second site mutation of IDH1 R132C, leading to IDH1 R132C/S280F, has emerged. We describe biochemical, crystallographic, and cellular studies on the IDH1 R132C/S280F and R132H/S280F variants that inform on the mechanism of second-site resistance, which involves both modulation of inhibitor binding at the IDH1 dimer-interface and alteration of kinetic properties, which enable more efficient 2-HG production relative to IDH1 R132C and IDH1 R132H. Importantly, the biochemical and cellular results demonstrate that it should be possible to overcome S280F mediated resistance in AML patients by using alternative inhibitors, including some presently in phase 2 clinical trials.

Identifiants

pubmed: 35970853
doi: 10.1038/s41467-022-32436-4
pii: 10.1038/s41467-022-32436-4
pmc: PMC9378673
doi:

Substances chimiques

Pyridines 0
Isocitrate Dehydrogenase EC 1.1.1.41
IDH1 protein, human EC 1.1.1.42.
ivosidenib Q2PCN8MAM6
Glycine TE7660XO1C

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4785

Subventions

Organisme : Biotechnology and Biological Sciences Research Council
ID : BB/R506655/1
Pays : United Kingdom
Organisme : Biotechnology and Biological Sciences Research Council
ID : BB/L000121/1
Pays : United Kingdom
Organisme : Biotechnology and Biological Sciences Research Council
ID : BB/J001694/2
Pays : United Kingdom
Organisme : Biotechnology and Biological Sciences Research Council
ID : BB/R013829/1
Pays : United Kingdom
Organisme : Wellcome Trust
ID : 091857/7/10/7
Pays : United Kingdom
Organisme : Medical Research Council
Pays : United Kingdom
Organisme : Cancer Research UK
ID : C8717/A18245
Pays : United Kingdom

Informations de copyright

© 2022. The Author(s).

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Auteurs

Raphael Reinbold (R)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK.

Ingvild C Hvinden (IC)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK.

Patrick Rabe (P)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK.

Ryan A Herold (RA)

Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK.

Alina Finch (A)

Institute of Cancer and Genomic Sciences, University of Birmingham, Birmingham, UK.

James Wood (J)

Institute of Cancer and Genomic Sciences, University of Birmingham, Birmingham, UK.
Institute of Genetics and Cancer, University of Edinburgh, Edinburgh, UK.

Melissa Morgan (M)

Institute of Cancer and Genomic Sciences, University of Birmingham, Birmingham, UK.
Institute of Genetics and Cancer, University of Edinburgh, Edinburgh, UK.

Maximillian Staudt (M)

Institute of Pharmaceutical Sciences, University of Freiburg, 79104, Freiburg, Germany.

Ian J Clifton (IJ)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK.

Fraser A Armstrong (FA)

Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK.

James S O McCullagh (JSO)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK.

Jo Redmond (J)

GlaxoSmithKline, Gunnels Wood Rd, Stevenage, SG1 2NY, UK.

Chiara Bardella (C)

Institute of Cancer and Genomic Sciences, University of Birmingham, Birmingham, UK.

Martine I Abboud (MI)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK. martine.abboud@lau.edu.
Department of Natural Sciences, Lebanese American University, Byblos/Beirut, Lebanon. martine.abboud@lau.edu.

Christopher J Schofield (CJ)

Chemistry Research Laboratory, Department of Chemistry and the Ineos Oxford Institute for Antimicrobial Research, University of Oxford, 12 Mansfield, Oxford, OX1 3TA, UK. christopher.schofield@chem.ox.ac.uk.

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Classifications MeSH