Synthesis of Carbamoyl Fluorides Using a Difluorophosgene Surrogate Derived from Difluorocarbene and Pyridine

Fluorides Hydrocarbons, Fluorinated Oxides Pyridines

Journal

The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R

Informations de publication

Date de publication:
02 09 2022
Historique:
pubmed: 17 8 2022
medline: 9 9 2022
entrez: 16 8 2022
Statut: ppublish

Résumé

We report a method for the synthesis of carbamoyl fluorides from secondary amines using bench-stable, inexpensive, and readily accessible starting materials that, when combined, yield a surrogate for toxic difluorophosgene (COF

Identifiants

DOI: 10.1021/acs.joc.2c01017 PMID: 35972076
pubmed: 35972076
doi: 10.1021/acs.joc.2c01017
doi:

Substances chimiques

Hydrocarbons, Fluorinated 0
Oxides 0
Pyridines 0
difluorocarbene 0
Fluorides Q80VPU408O

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

11457-11468

Auteurs

Dusty Cadwallader (D)

Department of Chemistry, York University, 4700 Keele Street, Toronto, Ontario M3J 1P3, Canada.
ORCID: 0000-0001-9484-8288

Tristan R Tiburcio (TR)

Department of Chemistry, York University, 4700 Keele Street, Toronto, Ontario M3J 1P3, Canada.

George A Cieszynski (GA)

Department of Chemistry, York University, 4700 Keele Street, Toronto, Ontario M3J 1P3, Canada.

Christine M Le (CM)

Department of Chemistry, York University, 4700 Keele Street, Toronto, Ontario M3J 1P3, Canada.
ORCID: 0000-0003-2543-4414

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Composés du fluor › Acide fluorhydrique › Fluorures › Synthesis of Carbamoyl Fluorides Using a...
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures halogénés › Hydrocarbures fluorés › Synthesis of Carbamoyl Fluorides Using a...
questionsmedicales.fr › Produits chimiques inorganiques › Composés de l'oxygène › Oxydes › Synthesis of Carbamoyl Fluorides Using a...
questionsmedicales.fr › Composés hétérocycliques › Composés hétéromonocycliques › Pyridines › Synthesis of Carbamoyl Fluorides Using a...