In-Situ Analysis of Anionic Coordination Polymerizations by Electrospray-Ionization Mass Spectrometry.
Analytical Methods
Cobalt
Mass Spectrometry
Polymerization
Reaction Mechanisms
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
24 Oct 2022
24 Oct 2022
Historique:
received:
12
07
2022
pubmed:
18
8
2022
medline:
18
8
2022
entrez:
17
8
2022
Statut:
ppublish
Résumé
Anionic coordination polymerizations proceed via highly reactive intermediates, whose in situ analysis has remained difficult. Here, we show that electrospray-ionization mass spectrometry is a promising method to obtain detailed information on the polymerization process. Focusing on polymerization reactions of 1,3-dienes initiated by CoCl
Identifiants
pubmed: 35977914
doi: 10.1002/anie.202210211
pmc: PMC9828445
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202210211Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : KO 2875/8-1
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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