The degradation of dissolved organic matter in black and odorous water by humic substance-mediated Fe(II)/Fe(III) cycle under redox fluctuation.

In nature, the hydroxyl radical (•OH) is produced during the anaerobic-aerobic transition when groundwater level fluctuates. In addition, the •OH is also detected in iron-bearing clay minerals and iron oxides during the redox process. Goethite is one of the most stable iron oxides involved in biogeochemical cycles. In this study, the coexisting humic acid (HA) enhanced the generation of Fe(II) during the iron reduction process and accelerated the generation of •OH in the redox process of goethite. The organic contaminants in black and odorous water were decomposed by constructing an iron-reducing bacteria-HA-Fe(II)/Fe(III) reaction system under anaerobic-aerobic alternation. The results demonstrated that in the anaerobic stage, HA could promote the reduction and dissolution of goethite through the complexation effect and electron shuttle mechanism, as well as significantly strengthening the iron reduction process in water. Under aerobic conditions, Fe(II) in the reaction system would activate O

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.