Reaching High Stereoselectivity and Activity in Organocatalyzed Ring-Opening Polymerization of Racemic Lactide by the Combined Use of a Chiral (Thio)Urea and a

Dioxanes Methane / analogs & derivatives Plastics Polyesters / chemistry Polymerization Stereoisomerism Thiourea Toluene Urea

Journal

ACS macro letters
ISSN: 2161-1653
Titre abrégé: ACS Macro Lett
Pays: United States
ID NLM: 101574672

Informations de publication

Date de publication:
20 Sep 2022
Historique:
pubmed: 7 9 2022
medline: 23 9 2022
entrez: 6 9 2022
Statut: ppublish

Résumé

Stereochemical control during polymerization is a key strategy of polymer chemistry to achieve semicrystalline engineered plastics. The stereoselective ring-opening polymerization (ROP) of racemic lactide (

Identifiants

DOI: 10.1021/acsmacrolett.2c00457 PMID: 36067070
pubmed: 36067070
doi: 10.1021/acsmacrolett.2c00457
doi:

Substances chimiques

Dioxanes 0
Plastics 0
Polyesters 0
carbene 2465-56-7
Toluene 3FPU23BG52
Urea 8W8T17847W
dilactide 95-96-5
Thiourea GYV9AM2QAG
Methane OP0UW79H66

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1148-1155

Auteurs

Mohamed Samir Zaky (MS)

Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, Université de Bordeaux, INP-ENSCBP, 16 av, Pey Berland, 33607 PESSAC Cedex France.

Anne-Laure Wirotius (AL)

Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, Université de Bordeaux, INP-ENSCBP, 16 av, Pey Berland, 33607 PESSAC Cedex France.

Olivier Coulembier (O)

Center of Innovation and Research in Materials and Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials, University of Mons, Mons B-7000, Belgium.
ORCID: 0000-0001-5753-7851

Gilles Guichard (G)

Univ. Bordeaux, CNRS, CBMN, UMR 5248, Institut Européen de Chimie et Biologie, 2 rue Robert Escarpit, F-33607 Pessac, France.
ORCID: 0000-0002-2584-7502

Daniel Taton (D)

Laboratoire de Chimie des Polymères Organiques (LCPO), UMR 5629, Université de Bordeaux, INP-ENSCBP, 16 av, Pey Berland, 33607 PESSAC Cedex France.
ORCID: 0000-0002-8539-4963

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Classifications MeSH

questionsmedicales.fr › Composés hétérocycliques › Composés hétéromonocycliques › Dioxanes › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures acycliques › Alcanes › Méthane › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Matières plastiques › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Polyesters › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Phénomènes chimiques › Polymérisation › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Composés chimiques organiques › Composés du soufre › Thiourée › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures cycliques › Hydrocarbures aromatiques › Dérivés du benzène › Toluène › Reaching High Stereoselectivity and Activity...
questionsmedicales.fr › Composés chimiques organiques › Amides › Urée › Reaching High Stereoselectivity and Activity...