Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility.
PEM reactor
enone
hydrogenation
iridium
palladium
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2022
2022
Historique:
received:
01
06
2022
accepted:
11
08
2022
entrez:
15
9
2022
pubmed:
16
9
2022
medline:
16
9
2022
Statut:
epublish
Résumé
Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).
Identifiants
pubmed: 36105727
doi: 10.3762/bjoc.18.107
pmc: PMC9443409
doi:
Types de publication
Journal Article
Langues
eng
Pagination
1055-1061Informations de copyright
Copyright © 2022, Mitsudo et al.
Références
RSC Adv. 2019 Jul 30;9(41):23560-23569
pubmed: 35530610
Org Biomol Chem. 2021 Sep 14;19(34):7363-7368
pubmed: 34612359
Beilstein J Org Chem. 2018 May 24;14:1192-1202
pubmed: 29977386
ChemSusChem. 2012 Dec;5(12):2410-20
pubmed: 22961747
Chem Commun (Camb). 2002 Jan 7;(1):32-3
pubmed: 12120296
Org Lett. 2021 Apr 16;23(8):3120-3124
pubmed: 33818115
Angew Chem Int Ed Engl. 2020 May 11;59(20):7803-7807
pubmed: 32077555