Enabling High-Stability of Aqueous-Processed Nickel-Rich Positive Electrodes in Lithium Metal Batteries.
Ni-rich cathodes
aqueous binders
ionic liquid electrolytes
lithium batteries
lithium metal
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Oct 2022
Oct 2022
Historique:
revised:
16
08
2022
received:
22
06
2022
pubmed:
19
9
2022
medline:
19
9
2022
entrez:
18
9
2022
Statut:
ppublish
Résumé
Lithium batteries occupy the large-scale electric mobility market raising concerns about the environmental impact of cell production, especially regarding the use of poly(vinylidene difluoride) (teratogenic) and N-methyl-2-pyrrolidone (NMP, harmful). To avoid their use, an aqueous electrode processing route is utilized in which a water-soluble hybrid acrylic-fluoropolymer together with sodium carboxymethyl cellulose is used as binder, and a thin phosphate coating layer is in situ formed on the surface of the nickel-rich cathode during electrode processing. The resulting electrodes achieve a comparable performance to that of NMP-based electrodes in conventional organic carbonate-based electrolyte (LP30). Subsequently, an ionic liquid electrolyte (ILE) is employed to replace the organic electrolyte, building stable electrode/electrolyte interphases on the surface of the nickel-rich positive electrode (cathode) and metallic lithium negative electrode (anode). In such ILE, the aqueously processed electrodes achieve high cycling stability with a capacity retention of 91% after 1000 cycles (20 °C). In addition, a high capacity of more than 2.5 mAh cm
Identifiants
pubmed: 36116115
doi: 10.1002/smll.202203874
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2203874Subventions
Organisme : Chinese Scholarship Council
Organisme : Helmholtz Association and the German Federal Ministry of Education and Research
Organisme : within the LILLINT
ID : 03XP0225D
Organisme : National Research Foundation of Korea
Organisme : Korea government
ID : NRF-2020R1A2C2009057
Organisme : Korea government
ID : NRF- 2021R1A4A200168711
Informations de copyright
© 2022 The Authors. Small published by Wiley-VCH GmbH.
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