Noncontact tip-enhanced Raman spectroscopy for nanomaterials and biomedical applications.


Journal

Nanoscale advances
ISSN: 2516-0230
Titre abrégé: Nanoscale Adv
Pays: England
ID NLM: 101738708

Informations de publication

Date de publication:
11 Sep 2019
Historique:
received: 23 05 2019
accepted: 16 08 2019
entrez: 22 9 2022
pubmed: 19 8 2019
medline: 19 8 2019
Statut: epublish

Résumé

Tip-enhanced Raman spectroscopy (TERS) has been established as one the most efficient analytical techniques for probing vibrational states with nanoscale resolution. While TERS may be a source of unique information about chemical structure and interactions, it has a limited use for materials with rough or sticky surfaces. Development of the TERS approach utilizing a non-contact scanning probe microscopy mode can significantly extend the number of applications. Here we demonstrate a proof of the concept and feasibility of a non-contact TERS approach and test it on various materials. Our experiments show that non-contact TERS can provide 10 nm spatial resolution and a Raman signal enhancement factor of 10

Identifiants

pubmed: 36133556
doi: 10.1039/c9na00322c
pii: c9na00322c
pmc: PMC9419720
doi:

Types de publication

Journal Article

Langues

eng

Pagination

3392-3399

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Dmitry N Voylov (DN)

Department of Mechanical Engineering, Tufts University Medford Massachusetts 02155 USA dmitry.voylov@tufts.edu dvoylov@utk.edu.
Chemical Sciences Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Vera Bocharova (V)

Chemical Sciences Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Nickolay V Lavrik (NV)

Center for Nanophase Materials Sciences, Computational Sciences and Engineering Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Ivan Vlassiouk (I)

Energy & Transportation Science Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Georgios Polizos (G)

Energy & Transportation Science Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Alexei Volodin (A)

Institute of Problems of Chemical Physics RAS Chernogolovka Moscow region 142432 Russia.

Yury M Shulga (YM)

National University of Science and Technology MISIS Moscow 119049 Russia.

Alexander Kisliuk (A)

Chemical Sciences Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Thirumagal Thiyagarajan (T)

Department of Medicine, University of Tennessee Health Science Center Memphis Tennessee 38103 USA.

Duane D Miller (DD)

Department of Pharmaceutical Sciences, University of Tennessee Health Science Center Memphis Tennessee 38103 USA.

Ramesh Narayanan (R)

Department of Medicine, University of Tennessee Health Science Center Memphis Tennessee 38103 USA.

Bobby G Sumpter (BG)

Center for Nanophase Materials Sciences, Computational Sciences and Engineering Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Alexei P Sokolov (AP)

Chemical Sciences Division, Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA.

Classifications MeSH