From starphenes to non-benzenoid linear conjugated polymers by substrate templating.
Journal
Nanoscale advances
ISSN: 2516-0230
Titre abrégé: Nanoscale Adv
Pays: England
ID NLM: 101738708
Informations de publication
Date de publication:
20 Apr 2021
20 Apr 2021
Historique:
received:
16
02
2021
accepted:
06
03
2021
entrez:
22
9
2022
pubmed:
8
3
2021
medline:
8
3
2021
Statut:
epublish
Résumé
Combining on-surface synthetic methods with the power of scanning tunneling microscopy to characterize novel materials at the single molecule level, we show how to steer the reactivity of one anthracene-based precursor towards different product nanostructures. Whereas using a Au(111) surface with three-fold symmetry results in the dominant formation of a starphene derivative, the two-fold symmetry of a reconstructed Au(110) surface allows the selective growth of non-benzenoid linear conjugated polymers. We further assess the electronic properties of each of the observed product structures
Identifiants
pubmed: 36133758
doi: 10.1039/d1na00126d
pii: d1na00126d
pmc: PMC9419161
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2351-2358Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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