Programed Thermoresponsive Polymers with Cleavage-Induced Phase Transition.

Anions Phase Transition Polymers / chemistry Stimuli Responsive Polymers Temperature Water / chemistry
cleavage reaction phase boundary thermoresponsive polymer

Journal

Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009

Informations de publication

Date de publication:
18 Sep 2022
Historique:
received: 02 09 2022
revised: 12 09 2022
accepted: 15 09 2022
entrez: 23 9 2022
pubmed: 24 9 2022
medline: 28 9 2022
Statut: epublish

Résumé

A new programed upper critical solution temperature-type thermoresponsive polymer was developed using water-soluble anionic polymer conjugates derived from polyallylamine and phthalic acid with cleavage-induced phase transition property. Intrinsic charge inversion from anion to cation of the polymer side chain is induced through a side chain cleavage reaction in acidic aqueous media. With the progress of side chain cleavage under fixed external conditions, the polymer conjugates express a thermoresponsive property, followed by shifting a phase boundary due to the change in polymer composition. When the phase transition boundary eventually reached the examined temperature, phase transition occurs under fixed external conditions. Such new insight obtained in this study opens up the new concept of time-programed stimuli-responsive polymer possessing a cleavage-induced phase transition.

Identifiants

DOI: 10.3390/molecules27186082 PMID: 36144815 PMC: PMC9501266
pubmed: 36144815
pii: molecules27186082
doi: 10.3390/molecules27186082
pmc: PMC9501266
pii:
doi:

Substances chimiques

Anions 0
Polymers 0
Stimuli Responsive Polymers 0
Water 059QF0KO0R

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Références

J Am Chem Soc. 2006 Oct 11;128(40):13046-7
pubmed: 17017772
Langmuir. 2004 Jun 22;20(13):5506-11
pubmed: 15986693
J Mater Chem B. 2020 Jan 28;8(4):607-628
pubmed: 31939978
ACS Macro Lett. 2013 Jul 16;2(7):597-600
pubmed: 35581788
J Biomater Sci Polym Ed. 2017 Jul - Aug;28(10-12):939-957
pubmed: 28277003
Biomaterials. 2009 Dec;30(36):6844-53
pubmed: 19783043
J Colloid Interface Sci. 2017 Mar 15;490:372-379
pubmed: 27914336
Expert Opin Drug Deliv. 2013 Dec;10(12):1669-86
pubmed: 24125490
Adv Drug Deliv Rev. 2019 Jan 1;138:167-192
pubmed: 30315832
J Mater Chem B. 2016 Oct 21;4(39):6381-6397
pubmed: 32263447
Chem Soc Rev. 2013 Sep 7;42(17):7214-43
pubmed: 23450220
Chem Commun (Camb). 2008 Nov 30;(44):5758-60
pubmed: 19009072
Chem Soc Rev. 2017 Feb 20;46(4):1193-1239
pubmed: 28165097
J Org Chem. 2020 Apr 3;85(7):4663-4671
pubmed: 32155066

Auteurs

Yukiya Kitayama (Y)

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
Department of Applied Chemistry, Graduate School of Engineering, Osaka Metropolitan University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.

Yasumichi Yazaki (Y)

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.

Junya Emoto (J)

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.

Eiji Yuba (E)

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
Department of Applied Chemistry, Graduate School of Engineering, Osaka Metropolitan University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
ORCID: 0000-0003-4984-2113

Atsushi Harada (A)

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
Department of Applied Chemistry, Graduate School of Engineering, Osaka Metropolitan University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
ORCID: 0000-0002-9485-2110

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Électrolytes › Ions › Anions › Programed Thermoresponsive Polymers with...
questionsmedicales.fr › Phénomènes chimiques › Transition de phase › Programed Thermoresponsive Polymers with...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Programed Thermoresponsive Polymers with...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Matériaux intelligents › Polymères réagissant aux stimuli › Programed Thermoresponsive Polymers with...
questionsmedicales.fr › Environnement et santé publique › Environnement › Concepts météorologiques › Atmosphère › Temps (météorologie) › Température › Programed Thermoresponsive Polymers with...
questionsmedicales.fr › Produits chimiques inorganiques › Composés de l'oxygène › Oxydes › Eau › Programed Thermoresponsive Polymers with...