Hierarchical Assembly of a Micro- and Macroporous Hydrogen-Bonded Organic Framework with Tailored Single-Crystal Size.
Crystal Growth
Hierarchical Assembly
Hydrogen-Bonded Organic Frameworks
Macropores
Micropores
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
21 Nov 2022
21 Nov 2022
Historique:
received:
14
06
2022
pubmed:
27
9
2022
medline:
27
9
2022
entrez:
26
9
2022
Statut:
ppublish
Résumé
Porous organic molecular materials represent an emergent field of research in Chemistry and Materials Science due to their unique combination of properties. To enhance their performance and expand the number of applications, the incorporation of hierarchical porosity is required, as exclusive microporosity entails several limitations. However, the integration of macropores in porous organic molecular materials is still an outstanding challenge. Herein, we report the first example of a hydrogen-bonded organic framework (MM-TPY) with hierarchical skeletal morphology, containing stable micro- and macroporosity. The crystal size, from micro to centimetre scale, can be controlled in a single step without using additives or templates. The mechanism of assembly during the crystal formation is compatible with a skeletal crystal growth. As proof of concept, we employed the hierarchical porosity as a platform for the dual, sequential and selective co-recognition of molecular species and microparticles.
Identifiants
pubmed: 36161683
doi: 10.1002/anie.202208677
pmc: PMC9827975
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202208677Subventions
Organisme : Ministerio de Ciencia e Inovacion
ID : PID2020-116998RB-I00
Organisme : MINECO
ID : PID2019-104778GB-I00
Organisme : Ministerio de Educación y Formación Profesional
ID : PRX21/00407
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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