Energy-Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal.
Cucurbituril
Iodine Adsorption
Porous Material
Supramolecular
Verkade Superbase
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
05 Dec 2022
05 Dec 2022
Historique:
received:
22
09
2022
pubmed:
6
10
2022
medline:
6
10
2022
entrez:
5
10
2022
Statut:
ppublish
Résumé
Recently, porous organic crystals (POC) based on macrocycles have shown exceptional sorption and separation properties. Yet, the impact of guest presence inside a macrocycle prior to adsorption has not been studied. Here we show that the inclusion of trimethoxybenzyl-azaphosphatrane in the macrocycle cucurbit[8]uril (CB[8]) affords molecular porous host⋅guest crystals (PHGC-1) with radically new properties. Unactivated hydrated PHGC-1 adsorbed iodine spontaneously and selectively at room temperature and atmospheric pressure. The absence of (i) heat for material synthesis, (ii) moisture sensitivity, and (iii) energy-intensive steps for pore activation are attractive attributes for decreasing the energy costs.
Identifiants
pubmed: 36198650
doi: 10.1002/anie.202214039
pmc: PMC10092189
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202214039Subventions
Organisme : European Union's Horizon 2020
ID : 713750
Organisme : A*MIDEX
ID : ANR-11- IDEX-0001-02
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
Références
Chemistry. 2007;13(29):8153-63
pubmed: 17639542
J Am Chem Soc. 2014 Sep 17;136(37):12828-31
pubmed: 25184689
Chem Rev. 2016 Feb 24;116(4):2478-601
pubmed: 26812185
Acc Chem Res. 2001 Apr;34(4):319-30
pubmed: 11308306
J Am Chem Soc. 2013 Aug 14;135(32):11684-7
pubmed: 23885835
Science. 2002 Nov 1;298(5595):1000-2
pubmed: 12411698
Acc Chem Res. 1996 Sep;29(9):441-9
pubmed: 23618410
Chemistry. 2014 Jul 7;20(28):8571-4
pubmed: 24888758
Nat Commun. 2016 Oct 13;7:13108
pubmed: 27734829
Chemistry. 2020 Feb 17;26(10):2154-2158
pubmed: 31803978
Angew Chem Int Ed Engl. 2010 Jul 12;49(30):5125-9
pubmed: 20572239
Angew Chem Int Ed Engl. 2004 Nov 26;43(46):6308-11
pubmed: 15558679
ACS Appl Mater Interfaces. 2018 Apr 4;10(13):10622-10626
pubmed: 29547256
ChemSusChem. 2017 Apr 10;10(7):1543-1553
pubmed: 28252246
Chem Rev. 2015 Nov 25;115(22):12320-406
pubmed: 26566008
Nat Mater. 2008 Feb;7(2):146-50
pubmed: 18193053
J Am Chem Soc. 2017 May 17;139(19):6574-6577
pubmed: 28463507
Angew Chem Int Ed Engl. 2019 Jul 22;58(30):10281-10284
pubmed: 31112359
J Am Chem Soc. 2010 Oct 20;132(41):14457-69
pubmed: 20866087
Angew Chem Int Ed Engl. 2022 Dec 5;61(49):e202214039
pubmed: 36198650
J Am Chem Soc. 2017 Mar 1;139(8):2908-2911
pubmed: 28182420
J Am Chem Soc. 2010 Mar 3;132(8):2561-3
pubmed: 20131766
J Am Chem Soc. 2018 Nov 7;140(44):14571-14575
pubmed: 30293426
Chem Soc Rev. 2012 Sep 21;41(18):6010-22
pubmed: 22821129
Angew Chem Int Ed Engl. 2020 Nov 23;59(48):21367-21371
pubmed: 32876969
Angew Chem Int Ed Engl. 2005 Aug 5;44(31):4844-70
pubmed: 16052668
Chemistry. 2022 Nov 16;28(64):e202201656
pubmed: 35980006
Chemistry. 2022 Jan 10;28(2):e202103336
pubmed: 34791726
Angew Chem Int Ed Engl. 2019 Jan 8;58(2):403-416
pubmed: 29978946
Chem Commun (Camb). 2014 Dec 21;50(98):15509-12
pubmed: 25307365
Inorg Chem. 2019 Oct 21;58(20):14145-14150
pubmed: 31566954
Chem Soc Rev. 2019 Mar 4;48(5):1362-1389
pubmed: 30676603
Angew Chem Int Ed Engl. 2017 Nov 13;56(46):14618-14621
pubmed: 28975721
Chem Rev. 1997 Oct 1;97(6):2373-2420
pubmed: 11848903
J Am Chem Soc. 2013 Nov 13;135(45):16912-25
pubmed: 24147834
Chem Soc Rev. 2015 Jan 21;44(2):394-418
pubmed: 25317670
J Am Chem Soc. 2022 Jul 13;144(27):12390-12399
pubmed: 35765245
Angew Chem Int Ed Engl. 2020 Mar 23;59(13):5355-5358
pubmed: 31951060
J Am Chem Soc. 2017 Jul 12;139(27):9186-9191
pubmed: 28661665
Chem Soc Rev. 2009 May;38(5):1450-9
pubmed: 19384447
Angew Chem Int Ed Engl. 2011 Nov 25;50(48):11386-90
pubmed: 21976397
Angew Chem Int Ed Engl. 2006 Feb 27;45(10):1585-8
pubmed: 16444790
Science. 2013 Aug 30;341(6149):1230444
pubmed: 23990564
Nature. 2011 Jun 15;474(7351):367-71
pubmed: 21677756
Chem Rev. 2020 Aug 26;120(16):8814-8933
pubmed: 31967791
Nature. 2021 Nov;599(7885):411-415
pubmed: 34789903
Science. 2010 Mar 26;327(5973):1627-30
pubmed: 20339069
Nat Chem. 2021 Oct;13(10):933-939
pubmed: 34239085
Acc Chem Res. 2018 Sep 18;51(9):2064-2072
pubmed: 30011181
Nat Mater. 2014 Oct;13(10):954-60
pubmed: 25038731
Chemistry. 2019 Feb 18;25(10):2497-2502
pubmed: 30565324
Angew Chem Int Ed Engl. 2019 Mar 18;58(12):3981-3985
pubmed: 30701668
J Am Chem Soc. 2018 Mar 7;140(9):3190-3193
pubmed: 29432675
Chem Rev. 2012 Feb 8;112(2):724-81
pubmed: 22204561
Science. 2001 Nov 30;294(5548):1907-11
pubmed: 11729312
Chem Soc Rev. 2007 Feb;36(2):236-45
pubmed: 17264926
Nat Chem. 2013 Oct;5(10):830-4
pubmed: 24056338
Angew Chem Int Ed Engl. 2008;47(18):3352-5
pubmed: 18357602
Angew Chem Int Ed Engl. 2018 Mar 26;57(14):3717-3721
pubmed: 29393989
J Am Chem Soc. 2017 Nov 1;139(43):15320-15323
pubmed: 29035524
Chem Sci. 2018 Oct 24;10(3):730-736
pubmed: 30809339
Angew Chem Int Ed Engl. 2018 Feb 5;57(6):1592-1595
pubmed: 29251391
J Am Chem Soc. 2019 Aug 7;141(31):12280-12287
pubmed: 31314522
Angew Chem Int Ed Engl. 2014 Feb 3;53(6):1516-20
pubmed: 24403008
Angew Chem Int Ed Engl. 2015 Jan 7;54(2):574-7
pubmed: 25394888
J Am Chem Soc. 2022 Jan 12;144(1):113-117
pubmed: 34962800
Nat Mater. 2009 Dec;8(12):973-8
pubmed: 19855385
J Am Chem Soc. 2001 Jun 20;123(24):5849-50
pubmed: 11403638
Angew Chem Int Ed Engl. 2016 Jun 20;55(26):7413-7
pubmed: 27119651
Angew Chem Int Ed Engl. 2016 Jun 20;55(26):7539-43
pubmed: 27167098
J Am Chem Soc. 2012 Dec 5;134(48):19935-41
pubmed: 23137118
J Am Chem Soc. 2010 Sep 8;132(35):12200-2
pubmed: 20718409
J Hazard Mater. 2021 Aug 15;416:125890
pubmed: 34492828
J Am Chem Soc. 2018 Jun 6;140(22):6921-6930
pubmed: 29754488
Acc Chem Res. 2003 Aug;36(8):621-30
pubmed: 12924959
Chemistry. 2019 Sep 25;25(54):12552-12559
pubmed: 31286592
Angew Chem Int Ed Engl. 2007;46(44):8342-56
pubmed: 17902079
J Am Chem Soc. 2017 Jul 19;139(28):9558-9565
pubmed: 28506068
Angew Chem Int Ed Engl. 2009;48(18):3273-7
pubmed: 19343755
ACS Appl Mater Interfaces. 2019 Jan 9;11(1):998-1003
pubmed: 30525365
Science. 2005 Nov 18;310(5751):1166-70
pubmed: 16293756
Angew Chem Int Ed Engl. 2011 Aug 16;50(34):7870-3
pubmed: 21721085
Angew Chem Int Ed Engl. 2002 Jul 2;41(13):2282-4
pubmed: 12203566
Acc Chem Res. 2014 Jul 15;47(7):2116-27
pubmed: 24784767