Circularly polarized luminescence from Tb(III) interacting with chiral polyether macrocycles.
Journal
Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234
Titre abrégé: Dalton Trans
Pays: England
ID NLM: 101176026
Informations de publication
Date de publication:
08 Nov 2022
08 Nov 2022
Historique:
pubmed:
12
10
2022
medline:
12
10
2022
entrez:
11
10
2022
Statut:
epublish
Résumé
A straightforward two-step synthesis protocol affords a series of chiral amide-based bis-pyridine substituted polyether macrocycles. One ligand is particularly able to complex terbium(III) ions spontaneously. Upon complexation, interesting chiroptical properties are observed both in absorbance (ECD) and in fluorescence (CPL). In ligand-centered electronic circular dichroism, a sign inversion coupled with a signal enhancement is measured; while an easily detectable metal-centered circularly polarized luminescence with a
Identifiants
pubmed: 36218085
doi: 10.1039/d2dt02627a
pmc: PMC9641584
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
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