Surface-Compartmentalized Micelles by Stereocomplex-Driven Self-Assembly.
block copolymers
crystallization-driven self-assembly
particulate surfactants
patchy micelles
stereocomplexes
Journal
Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239
Informations de publication
Date de publication:
Feb 2023
Feb 2023
Historique:
revised:
11
10
2022
received:
10
08
2022
pubmed:
27
10
2022
medline:
10
2
2023
entrez:
26
10
2022
Statut:
ppublish
Résumé
The unique corona structure of surface-compartmentalized micelles (Janus micelles, patchy micelles) opens highly relevant applications, e.g. as efficient particulate surfactants for emulsion stabilization or compatibilization of polymer blends. Here, stereocomplex-driven self-assembly (SCDSA) as a facile route to micelles with a semicrystalline stereocomplex (SC) core and a patch-like microphase separated corona, employing diblock copolymers with enantiomeric poly(L-lactide)/poly(D-lactide) blocks and highly incompatible corona-forming blocks (polystyrene (PS), poly(tert-butyl methacrylate)) is introduced. The spherical patchy SC micelles feature a narrow size distribution and show a compartmentalized, shamrock-like corona structure. Compared to SC micelles with a homogeneous PS corona the patchy micelles have a significantly higher interfacial activity attributable to the synergistic combination of an amphiphilic corona with the Pickering effect of nanoparticles. The patchy micelles are successfully employed in the stabilization of emulsions, underlining their application potential.
Identifiants
pubmed: 36285394
doi: 10.1002/marc.202200682
doi:
Substances chimiques
Micelles
0
Polymers
0
Surface-Active Agents
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2200682Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : SCHM2428/3-1
Informations de copyright
© 2022 The Authors. Macromolecular Rapid Communications published by Wiley-VCH GmbH.
Références
A. H. Gröschel, A. H. E. Müller, Nanoscale 2015, 7, 11841.
M. Karayianni, S. Pispas, J. Polym. Sci. 2021, 59, 1874.
Y. Lu, J. Lin, L. Wang, L. Zhang, C. Cai, Chem. Rev. 2020, 120, 4111.
A. K. Pearce, T. R. Wilks, M. C. Arno, R. K. O'Reilly, Nat. Rev. Chem. 2021, 5, 21.
U. Tritschler, S. Pearce, J. Gwyther, G. R. Whittell, I. Manners, Macromolecules 2017, 50, 3439.
M. Vafaeezadeh, W. R. Thiel, Angew. Chem., Int. Ed. 2022, 61, e202206403.
J. Du, R. K. O'Reilly, Chem. Soc. Rev. 2011, 40, 2402.
A. Walther, A. H. E. Müller, Chem. Rev. 2013, 113, 5194.
Q. Yang, K. Loos, Polym. Chem. 2017, 8, 641.
X. Fan, J. Yang, X. J. Loh, Z. Li, Macromol. Rapid Commun. 2019, 40, 1800203.
R. Deng, F. Liang, J. Zhu, Z. Yang, Mater. Chem. Front. 2017, 1, 431.
G. Agrawal, R. Agrawal, ACS Appl. Nano Mater. 2019, 2, 1738.
T. Pelras, C. S. Mahon, M. Müllner, Angew. Chem., Int. Ed. 2018, 57, 6982.
C. Hils, I. Manners, J. Schöbel, H. Schmalz, Polymers 2021, 13, 1481.
S. Song, X. Liu, E. Nikbin, J. Y. Howe, Q. Yu, I. Manners, M. A. Winnik, J. Am. Chem. Soc. 2021, 143, 6266.
J. Schöbel, M. Karg, D. Rosenbach, G. Krauss, A. Greiner, H. Schmalz, Macromolecules 2016, 49, 2761.
J. R. Finnegan, D. J. Lunn, O. E. C. Gould, Z. M. Hudson, G. R. Whittell, M. A. Winnik, I. Manners, J. Am. Chem. Soc. 2014, 136, 13835.
A. M. Oliver, J. Gwyther, M. A. Winnik, I. Manners, Macromolecules 2018, 51, 222.
S. Ganda, M. H. Stenzel, Prog. Polym. Sci. 2020, 101, 101195.
L. MacFarlane, C. Zhao, J. Cai, H. Qiu, I. Manners, Chem. Sci. 2021, 12, 4661.
J. Xu, H. Zhou, Q. Yu, I. Manners, M. A. Winnik, J. Am. Chem. Soc. 2018, 140, 2619.
J. Schmelz, M. Karg, T. Hellweg, H. Schmalz, ACS Nano 2011, 5, 9523.
H. Tsuji, Adv. Drug Delivery Rev. 2016, 107, 97.
Z. Li, B. H. Tan, T. Lin, C. He, Prog. Polym. Sci. 2016, 62, 22.
D. Sawai, Y. Tsugane, M. Tamada, T. Kanamoto, M. Sungil, S.-H. Hyon, J. Polym. Sci., Part B: Polym. Phys. 2007, 45, 2632.
H. Niu, J. Li, Q. Cai, X. Wang, F. Luo, J. Gong, Z. Qiang, J. Ren, Langmuir 2020, 36, 13881.
R. Liu, B. He, D. Li, Y. Lai, J. Z. Tang, Z. Gu, Macromol. Rapid Commun. 2012, 33, 1061.
W. Zhang, D. Zhang, X. Fan, G. Bai, Y. Guo, Z. Hu, RSC Adv. 2016, 6, 20761.
S. Noack, D. Schanzenbach, J. Koetz, H. Schlaad, Macromol. Rapid Commun. 2019, 40, 1800639.
L. Sun, A. Pitto-Barry, N. Kirby, T. L. Schiller, A. M. Sanchez, M. A. Dyson, J. Sloan, N. R. Wilson, R. K. O'Reilly, A. P. Dove, Nat. Commun. 2014, 5, 5746.
X. Fan, Z. Wang, D. Yuan, Y. Sun, Z. Li, C. He, Polym. Chem. 2014, 5, 4069.
Z. Li, D. Yuan, X. Fan, B. H. Tan, C. He, Langmuir 2015, 31, 2321.
F. K. Wolf, A. M. Hofmann, H. Frey, Macromolecules 2010, 43, 3314.
X. Hou, Q. Li, A. Cao, Macromol. Chem. Phys. 2013, 214, 1569.
D. Portinha, F. Boué, L. Bouteiller, G. Carrot, C. Chassenieux, S. Pensec, G. Reiter, Macromolecules 2007, 40, 4037.
D. Portinha, L. Bouteiller, S. Pensec, A. Richez, C. Chassenieux, Macromolecules 2004, 37, 3401.
S. H. Kim, J. P. K. Tan, F. Nederberg, K. Fukushima, Y. Y. Yang, R. M. Waymouth, J. L. Hedrick, Macromolecules 2009, 42, 25.
V. Ladelta, K. Ntetsikas, G. Zapsas, N. Hadjichristidis, Macromolecules 2022, 55, 2832.
A. Arkanji, V. Ladelta, K. Ntetsikas, N. Hadjichristidis, Polymers 2022, 14, 2431.
R. M. Michell, A. J. Müller, Prog. Polym. Sci. 2016, 54-55, 183.
Y. Lan, J. Choi, H. Li, Y. Jia, R. Huang, K. J. Stebe, D. Lee, Ind. Eng. Chem. Res. 2019, 58, 20961.
W. Yu, M. Inam, J. R. Jones, A. P. Dove, R. K. O'Reilly, Polym. Chem. 2017, 8, 5504.
S. Karanam, H. Goossens, B. Klumperman, P. Lemstra, Macromolecules 2003, 36, 3051.
C. Cheng, E. Khoshdel, K. L. Wooley, Macromolecules 2005, 38, 9455.