Multiscale Reciprocal Space Mapping of Magnetite Mesocrystals.

magnetite mesocrystals microscopic structure multiple-length-scale structures supercrystallography

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Jan 2023
Historique:
revised: 04 10 2022
received: 05 08 2022
pubmed: 29 10 2022
medline: 29 10 2022
entrez: 28 10 2022
Statut: ppublish

Résumé

Mesocrystals are a class of nanostructured material, where a multiple-length-scale structure is a prerequisite of many interesting phenomena. Resolving the mesocrystal structure is quite challenging due to their structuration on different length scales. The combination of small- and wide-angle X-ray scattering (SAXS and WAXS) techniques offers the possibility of non-destructively probing mesocrystalline structures simultaneously, over multiple length scales to reveal their microscopic structure. This work describes how high dynamical range of modern detectors sheds light on the weak features of scattering, significantly increasing the information content. The detailed analysis of X-ray diffraction (XRD) from the magnetite mesocrystals with different particle sizes and shapes is described, in tandem with electron microscopy. The revealed features provide valuable input to the models of mesocrystal growth and the choice of structural motif; the impact on magnetic properties is discussed.

Identifiants

pubmed: 36305045
doi: 10.1002/adma.202207130
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2207130

Subventions

Organisme : Deutsche Forschungsgemeinschaft
Organisme : Horizon 2020 research and innovation program of the European Union
ID : 715620
Organisme : European Research Council
Pays : International

Informations de copyright

© 2022 The Authors. Advanced Materials published by Wiley-VCH GmbH.

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Auteurs

Aleksandra Chumakova (A)

European Synchrotron Radiation Facility, 71 Avenue des Martyrs, Grenoble, 38000, France.
Outstation at Heinz Maier-Leibnitz Zentrum (MLZ), Institute of Crystallography (IfK), RWTH Aachen University, Lichtenbergstrasse 1, 85747, Garching, Germany.

Tristan Steegemans (T)

Julian Schlotheuber and Elena V. Sturm, Department of Chemistry, University of Konstanz, Universitaetsstraße 10, 78457, Konstanz, Germany.

Igor A Baburin (IA)

Department of Chemistry, TU Dresden, Bergstraße 66b, 01062, Dresden, Germany.

Alexander Mistonov (A)

Department of Physics, University of Konstanz, Universitätsstraße 10, 78457, Konstanz, Germany.

Ilya S Dubitskiy (IS)

Julian Schlotheuber and Elena V. Sturm, Department of Chemistry, University of Konstanz, Universitaetsstraße 10, 78457, Konstanz, Germany.

Julian Schlotheuber (J)

Julian Schlotheuber and Elena V. Sturm, Department of Chemistry, University of Konstanz, Universitaetsstraße 10, 78457, Konstanz, Germany.

Felizitas Kirner (F)

European Synchrotron Radiation Facility, 71 Avenue des Martyrs, Grenoble, 38000, France.
Department of Earth and Environmental Sciences, Section of Crystallography, Ludwig-Maximilians-Universität München (LMU), Theresienstr. 41C, 80333, Munich, Germany.

Sebastian Sturm (S)

Leibniz Institute for Solid State and Materials Research (IFW) Dresden, Helmholtzstraße 20, 01069, Dresden, Germany.
Fakultät für Chemie und Pharmazie - Physikalische Chemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, 81377, München, Germany.

Axel Lubk (A)

Leibniz Institute for Solid State and Materials Research (IFW) Dresden, Helmholtzstraße 20, 01069, Dresden, Germany.

Knut Müller-Caspary (K)

Fakultät für Chemie und Pharmazie - Physikalische Chemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, 81377, München, Germany.

Ilona Wimmer (I)

Department of Physics, University of Konstanz, Universitätsstraße 10, 78457, Konstanz, Germany.

Mikhail Fonin (M)

Department of Physics, University of Konstanz, Universitätsstraße 10, 78457, Konstanz, Germany.

Elena V Sturm (EV)

Department of Earth and Environmental Sciences, Section of Crystallography, Ludwig-Maximilians-Universität München (LMU), Theresienstr. 41C, 80333, Munich, Germany.

Alexeï Bosak (A)

European Synchrotron Radiation Facility, 71 Avenue des Martyrs, Grenoble, 38000, France.

Classifications MeSH