The Transformation of Inorganic to Organic Carbonates: Chasing for Reaction Pathways in Mechanochemistry.
alkali metals
mechanochemistry
nucleophilic substitution
quantum chemical calculations
time-resolved X-ray diffraction
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
01 Feb 2023
01 Feb 2023
Historique:
received:
13
09
2022
pubmed:
1
11
2022
medline:
1
11
2022
entrez:
31
10
2022
Statut:
ppublish
Résumé
Mechanochemical reactions are solvent-free alternatives to solution-based syntheses enabling even conventionally impossible transformations. Their reaction pathways, however, usually remain unexplored within the heavily vibrating, dense milling vessels. Here, we showcase how the green organic solvent diethyl carbonate is synthesized mechanochemically from inorganic alkali carbonates and how the complementary combination of milling parameter studies, synchrotron X-ray diffraction real time monitoring, and quantum chemical calculations reveal the underlying reaction pathways. With this, reaction intermediates are identified, and chemical concepts of solution-chemistry are challenged or corroborated for mechanochemistry.
Identifiants
pubmed: 36314665
doi: 10.1002/chem.202202860
pmc: PMC10107195
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202202860Subventions
Organisme : DFG
ID : 4538/7-1
Informations de copyright
© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
Références
Chemistry. 2023 Feb 1;29(7):e202202860
pubmed: 36314665
Chem Commun (Camb). 2014 Feb 14;50(13):1585-7
pubmed: 24382417
Chem Soc Rev. 2015 May 21;44(10):3079-116
pubmed: 25793366
Chemistry. 2022 Mar 1;28(13):e202104409
pubmed: 35041251
Adv Mater. 2016 Jul;28(27):5747-54
pubmed: 26932541
Chemistry. 2012 Jul 2;18(27):8464-73
pubmed: 22648998
J Am Chem Soc. 2016 Mar 9;138(9):2929-32
pubmed: 26894258
J Org Chem. 2005 Mar 18;70(6):2219-24
pubmed: 15760208
Chem Commun (Camb). 2021 Feb 2;57(9):1080-1092
pubmed: 33438694
Faraday Discuss. 2014;170:267-86
pubmed: 25406485
Chem Rev. 2010 Aug 11;110(8):4554-81
pubmed: 20345182
Nat Commun. 2021 Oct 21;12(1):6134
pubmed: 34675198
Angew Chem Int Ed Engl. 2022 May 16;61(21):e202117270
pubmed: 35128778
Chemistry. 2020 Feb 6;26(8):1811-1818
pubmed: 31756261
Nat Protoc. 2021 Jul;16(7):3492-3521
pubmed: 34089023
Chem Commun (Camb). 2020 Sep 14;56(71):10329-10332
pubmed: 32760966
Chem Commun (Camb). 2018 Nov 22;54(94):13216-13219
pubmed: 30403231
Nat Chem. 2013 Jan;5(1):66-73
pubmed: 23247180
ChemSusChem. 2022 Jan 10;15(1):e202101975
pubmed: 34731534
Chem Soc Rev. 2012 Jan 7;41(1):413-47
pubmed: 21892512