Self-assembled Ru(bda) Coordination Oligomers as Efficient Catalysts for Visible Light-Driven Water Oxidation in Pure Water.
Artificial Photosynthesis
Coordination Oligomer
Photocatalysis
Ruthenium Complexes
Water Oxidation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
23 Dec 2022
23 Dec 2022
Historique:
received:
03
08
2022
pubmed:
1
11
2022
medline:
1
11
2022
entrez:
31
10
2022
Statut:
ppublish
Résumé
Water-soluble multinuclear complexes based on ruthenium 2,2'-bipyridine-6,6'-dicarboxylate (bda) and ditopic bipyridine linker units are investigated in three-component visible light-driven water oxidation catalysis. Systematic studies revealed a strong enhancement of the catalytic efficiency in the absence of organic co-solvents and with increasing oligomer length. In-depth kinetic and morphological investigations suggest that the enhanced performance is induced by the self-assembly of linear Ru(bda) oligomers into aggregated superstructures. The obtained turnover frequencies (up to 14.9 s
Identifiants
pubmed: 36315034
doi: 10.1002/anie.202211445
pmc: PMC10100213
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202211445Subventions
Organisme : H2020 European Research Council
ID : 787937
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
Références
J Am Chem Soc. 2019 Apr 10;141(14):5565-5580
pubmed: 30889353
J Magn Reson. 2016 Jun;267:54-62
pubmed: 27116223
J Am Chem Soc. 2021 Feb 17;143(6):2484-2490
pubmed: 33538597
Chemistry. 2021 Jan 4;27(1):444-450
pubmed: 33241573
Science. 2016 Jan 22;351(6271):aad1920
pubmed: 26798020
Nat Chem. 2016 Jun;8(6):576-83
pubmed: 27219702
ChemSusChem. 2015 Nov;8(21):3688-96
pubmed: 26423045
Inorg Chem. 2021 Sep 6;60(17):13299-13308
pubmed: 34375524
Chem Rev. 2014 Dec 24;114(24):11863-2001
pubmed: 25354019
Chem Soc Rev. 2021 Mar 1;50(4):2444-2485
pubmed: 33404560
Angew Chem Int Ed Engl. 2021 Jun 21;60(26):14504-14511
pubmed: 33861495
Chem Soc Rev. 2017 Oct 16;46(20):6170-6193
pubmed: 28861558
Chem Soc Rev. 2016 Oct 7;45(19):5311-57
pubmed: 27218823
Nat Mater. 2011 Mar;10(3):176-88
pubmed: 21336298
Chem Rev. 2015 Dec 9;115(23):12974-3005
pubmed: 26151088
Inorg Chem. 2016 Nov 21;55(22):12024-12035
pubmed: 27802025
Angew Chem Int Ed Engl. 2016 May 17;55(21):6229-34
pubmed: 27071858
Chem Sci. 2020 Nov 16;12(1):50-70
pubmed: 34168739
Inorg Chem. 2019 Dec 16;58(24):16537-16545
pubmed: 31774669
Angew Chem Int Ed Engl. 2022 Dec 23;61(52):e202211445
pubmed: 36315034
J Am Chem Soc. 2009 Aug 5;131(30):10397-9
pubmed: 19601625
Chem Soc Rev. 2013 Feb 21;42(4):1847-70
pubmed: 22850767
Nat Chem. 2012 Mar 25;4(5):418-23
pubmed: 22522263
Inorg Chem. 2010 Jan 4;49(1):209-15
pubmed: 19994841
Nat Chem. 2019 Feb;11(2):146-153
pubmed: 30510216
J Am Chem Soc. 2021 Aug 4;143(30):11651-11661
pubmed: 34293261
Chem Soc Rev. 2014 Nov 21;43(22):7501-19
pubmed: 24473472