Rhodium Single-Atom Catalyst Design through Oxide Support Modulation for Selective Gas-Phase Ethylene Hydroformylation.
DFT
Olefin Valorization
Oxygen Vacancies
Single-Atom-Catalysts
X-Ray Absorption Spectroscopy
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
02 Jan 2023
02 Jan 2023
Historique:
received:
22
09
2022
pubmed:
1
11
2022
medline:
1
11
2022
entrez:
31
10
2022
Statut:
ppublish
Résumé
A frontier challenge in single-atom (SA) catalysis is the design of fully inorganic sites capable of emulating the high reaction selectivity traditionally exclusive of organometallic counterparts in homogeneous catalysis. Modulating the direct coordination environment in SA sites, via the exploitation of the oxide support's surface chemistry, stands as a powerful albeit underexplored strategy. We report that isolated Rh atoms stabilized on oxygen-defective SnO
Identifiants
pubmed: 36315420
doi: 10.1002/anie.202214048
pmc: PMC10099584
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202214048Subventions
Organisme : H2020 European Research Council
ID : 864195
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : RTI2018-096399-A-I00
Organisme : Ministerio de Ciencia e Innovación
ID : PID2019-104739GB-100/AEI/10.13039/501100011033
Organisme : Gobierno de Aragón
ID : DGA E13-20R
Organisme : Horizon 2020 Framework Programme
ID : 823717
Organisme : Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg
ID : RV bw17D011
Organisme : Helmholtz-Gemeinschaft
Organisme : Ministerio de educación de España
ID : FPU17/04701
Organisme : Ministerio de Educación de España
ID : FPU17/04751
Organisme : Spanish National Plan for Scientific and Technical Research and Innovation
ID : PRE2019-087571
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
Références
J Am Chem Soc. 2020 Oct 28;142(43):18378-18386
pubmed: 32955265
Angew Chem Int Ed Engl. 2011 Mar 14;50(12):2841-4
pubmed: 21387501
Materials (Basel). 2017 Dec 07;10(12):
pubmed: 29215556
Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16054-16058
pubmed: 27862789
Nat Commun. 2020 Jun 26;11(1):3220
pubmed: 32591532
J Am Chem Soc. 2019 Feb 13;141(6):2451-2461
pubmed: 30640467
J Am Chem Soc. 2020 Sep 2;142(35):14890-14902
pubmed: 32786735
Nat Commun. 2019 Mar 25;10(1):1358
pubmed: 30911011
Nano Lett. 2021 Sep 8;21(17):7309-7316
pubmed: 34410724
Chem Rev. 2018 May 23;118(10):4981-5079
pubmed: 29658707
Acc Chem Res. 2014 Mar 18;47(3):783-92
pubmed: 24266870
Angew Chem Int Ed Engl. 2018 Nov 19;57(47):15410-15414
pubmed: 30207630
Angew Chem Int Ed Engl. 2013 May 3;52(19):5101-5
pubmed: 23576363
J Am Chem Soc. 2019 Sep 18;141(37):14515-14519
pubmed: 31476119
J Am Chem Soc. 2007 Jul 11;129(27):8487-99
pubmed: 17555314
Angew Chem Int Ed Engl. 2020 Mar 27;59(14):5806-5815
pubmed: 31903674
Nat Commun. 2021 Jun 2;12(1):3295
pubmed: 34078894
Science. 2017 Mar 31;355(6332):1399-1403
pubmed: 28360324
J Chem Phys. 2010 Apr 21;132(15):154104
pubmed: 20423165
Nat Commun. 2021 Aug 4;12(1):4698
pubmed: 34349125
J Am Chem Soc. 2020 Apr 22;142(16):7425-7433
pubmed: 32174114
Chem Rev. 2012 Nov 14;112(11):5675-732
pubmed: 22937803
Nat Mater. 2017 Jan;16(1):132-138
pubmed: 27669051
Nat Commun. 2021 Sep 14;12(1):5422
pubmed: 34521832
Angew Chem Int Ed Engl. 2020 Oct 12;59(42):18586-18590
pubmed: 32643319
Angew Chem Int Ed Engl. 2023 Jan 2;62(1):e202214048
pubmed: 36315420
Angew Chem Int Ed Engl. 2018 Nov 19;57(47):15316-15329
pubmed: 30080958
Nat Commun. 2021 Feb 9;12(1):895
pubmed: 33563970
Nat Commun. 2019 Oct 8;10(1):4585
pubmed: 31594928
Science. 2016 Jul 8;353(6295):150-4
pubmed: 27387946
Nat Nanotechnol. 2010 Dec;5(12):843-7
pubmed: 21102466
Phys Rev Lett. 1996 Oct 28;77(18):3865-3868
pubmed: 10062328
J Am Chem Soc. 2020 Mar 18;142(11):5087-5096
pubmed: 32141745