Origin of the polychromatic photoluminescence of zeolite confined Ag clusters: temperature- and co-cation-dependent luminescence.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
12 Oct 2022
Historique:
received: 07 06 2022
accepted: 17 08 2022
entrez: 2 11 2022
pubmed: 3 11 2022
medline: 3 11 2022
Statut: epublish

Résumé

Zeolite confined silver clusters (AgCLs) have attracted extensive attention due to their remarkable luminescent properties, but the elucidation of the underlying photophysical processes and especially the excited-state dynamics remains a challenge. Herein, we investigate the bright photoluminescence of AgCLs confined in Linde Type A zeolites (LTA) by systematically varying the temperature (298-77 K) and co-cation composition (Li/Na) and examining their respective influence on the steady-state and time-resolved photoluminescence. The observed polychromatic emission of the tetrahedral Ag

Identifiants

pubmed: 36320393
doi: 10.1039/d2sc03197c
pii: d2sc03197c
pmc: PMC9555561
doi:

Types de publication

Journal Article

Langues

eng

Pagination

11560-11569

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Li Sun (L)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.

Masoumeh Keshavarz (M)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.

Giacomo Romolini (G)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.

Bjorn Dieu (B)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.

Johan Hofkens (J)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.
KU Leuven Core Facility for Advanced Spectroscopy Celestijnenlaan 200F 3001 Leuven Belgium mark.vanderauweraer@kuleuven.be.

Flip de Jong (F)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.

Eduard Fron (E)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.
KU Leuven Core Facility for Advanced Spectroscopy Celestijnenlaan 200F 3001 Leuven Belgium mark.vanderauweraer@kuleuven.be.

Maarten B J Roeffaers (MBJ)

Chem&Tech - Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium maarten.roeffaers@kuleuven.be.

Mark Van der Auweraer (M)

Chem&Tech - Molecular Imaging and Photonics, KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium eduard.fron@kuleuven.be.
KU Leuven Core Facility for Advanced Spectroscopy Celestijnenlaan 200F 3001 Leuven Belgium mark.vanderauweraer@kuleuven.be.

Classifications MeSH