Insights into the Complexation Mechanism of a Promising Lipophilic PyTri Ligand for Actinide Partitioning from Spent Nuclear Fuel.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
21 Nov 2022
Historique:
pubmed: 5 11 2022
medline: 5 11 2022
entrez: 4 11 2022
Statut: ppublish

Résumé

The challenging issue of spent nuclear fuel (SNF) management is being tackled by developing advanced technologies that point to reduce environmental footprint, long-term radiotoxicity, volumes and residual heat of the final waste, and to increase the proliferation resistance. The advanced recycling strategy provides several promising processes for a safer reprocessing of SNF. Advanced hydrometallurgical processes can extract minor actinides directly from Plutonium and Uranium Reduction Extraction raffinate by using selective hydrophilic and lipophilic ligands. This research is focused on a recently developed

Identifiants

pubmed: 36331210
doi: 10.1021/acs.inorgchem.2c02332
pmc: PMC9682475
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

18400-18411

Références

Inorg Chem. 2019 Nov 4;58(21):14642-14651
pubmed: 31609595
Ind Eng Chem Res. 2022 Mar 30;61(12):4436-4444
pubmed: 35370355
Chem Soc Rev. 2017 Dec 7;46(23):7229-7273
pubmed: 29111553
Inorg Chem. 2013 Apr 1;52(7):3414-28
pubmed: 22867058
Dalton Trans. 2013 Oct 21;42(39):14068-74
pubmed: 23752678
Inorg Chem. 2014 Nov 17;53(22):12135-40
pubmed: 25372998
Inorg Chem. 2002 Dec 30;41(26):7031-41
pubmed: 12495341
Inorg Chem. 2014 Mar 3;53(5):2450-9
pubmed: 24506462
J Am Chem Soc. 2016 Jun 15;138(23):7232-5
pubmed: 27203357
Dalton Trans. 2006 Apr 7;(13):1645-53
pubmed: 16547539
Chem Sci. 2015 Feb 1;6(2):1548-1561
pubmed: 29560242
Inorg Chem. 2017 Feb 20;56(4):2135-2144
pubmed: 28151663
Dalton Trans. 2018 Aug 14;47(32):10906-10914
pubmed: 30043815
Chem Sci. 2015 Aug 1;6(8):4812-4821
pubmed: 29142716
Dalton Trans. 2016 Nov 15;45(45):18102-18112
pubmed: 27488559
Anal Chim Acta. 2010 Sep 30;678(2):140-8
pubmed: 20888445

Auteurs

Francesco Galluccio (F)

Department of Energy, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano20133, Italy.

Elena Macerata (E)

Department of Energy, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano20133, Italy.

Patrik Weßling (P)

Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, Karlsruhe76021, Germany.
Institute for Physical Chemistry, Heidelberg University, Im Neuenheimer Feld 253, Heidelberg69120, Germany.

Christian Adam (C)

Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, Karlsruhe76021, Germany.

Eros Mossini (E)

Department of Energy, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano20133, Italy.

Walter Panzeri (W)

C.N.R.─Consiglio Nazionale Delle Ricerche, Istituto di Scienze e Tecnologie Chimiche "G. Natta" (SCITEC), Sezione "U.O.S. Milano Politecnico", Milan20133, Italy.

Mario Mariani (M)

Department of Energy, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano20133, Italy.

Andrea Mele (A)

C.N.R.─Consiglio Nazionale Delle Ricerche, Istituto di Scienze e Tecnologie Chimiche "G. Natta" (SCITEC), Sezione "U.O.S. Milano Politecnico", Milan20133, Italy.
Department of Chemistry, Materials and Chemical Engineering "G. Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano20133, Italy.

Andreas Geist (A)

Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, Karlsruhe76021, Germany.

Petra J Panak (PJ)

Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, Karlsruhe76021, Germany.
Institute for Physical Chemistry, Heidelberg University, Im Neuenheimer Feld 253, Heidelberg69120, Germany.

Classifications MeSH