Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT).
Journal
RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657
Informations de publication
Date de publication:
27 Oct 2022
27 Oct 2022
Historique:
received:
18
10
2022
accepted:
27
10
2022
entrez:
9
11
2022
pubmed:
10
11
2022
medline:
10
11
2022
Statut:
epublish
Résumé
Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and branching has been evaluated. Elevated temperature limits telomer length, thereby allowing a >10% reduction in the amount of telogen required to produce near identical high molecular weight branched polymers.
Identifiants
pubmed: 36349025
doi: 10.1039/d2ra06578a
pii: d2ra06578a
pmc: PMC9627727
doi:
Types de publication
Journal Article
Langues
eng
Pagination
31424-31431Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
SPR, SRC and PC are co-inventors on patents that protect the TBRT chemistry; these patents have been licensed to Scott Bader and form the basis of Polymer Mimetics Ltd (Company number 12598928).
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