Schlenk's Legacy-Methyllithium Put under Close Scrutiny.
Lithium
Methyl
NMR Spectroscopy
Nitrogen Ligand
X-Ray Diffractometry
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 Feb 2023
01 Feb 2023
Historique:
received:
04
10
2022
pubmed:
22
11
2022
medline:
22
11
2022
entrez:
21
11
2022
Statut:
ppublish
Résumé
Commercially available stock solutions of organolithium reagents are well-implemented tools in organic and organometallic chemistry. However, such solutions are inherently contaminated with lithium halide salts, which can complicate certain synthesis protocols and purification processes. Here, we report the isolation of chloride-free methyllithium employing K[N(SiMe
Identifiants
pubmed: 36409199
doi: 10.1002/anie.202214599
pmc: PMC10108226
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202214599Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : INST 40/575-1 FUGG
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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