Hydrogen Production and Carbon Capture by Gas-Phase Methane Pyrolysis: A Feasibility Study.
carbon capture
decarbonization
gas-phase chemistry
hydrogen production
methane pyrolysis
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
22 Mar 2023
22 Mar 2023
Historique:
revised:
17
11
2022
received:
26
10
2022
pubmed:
23
11
2022
medline:
23
11
2022
entrez:
22
11
2022
Statut:
ppublish
Résumé
Using natural gas and sustainable biogas as feed, high-temperature pyrolysis represents a potential technology for large-scale hydrogen production and simultaneous carbon capture. Further utilization of solid carbon accruing during the process (i. e., in battery industry or for metallurgy) increases the process's economic chances. This study demonstrated the feasibility of gas-phase methane pyrolysis for hydrogen production and carbon capture in an electrically heated high-temperature reactor operated between 1200 and 1600 °C under industrially relevant conditions. While hydrogen addition controlled methane conversion and suppressed the formation of undesired byproducts, an increasing residence time decreased the amount of byproducts and benefited high hydrogen yields. A temperature of 1400 °C ensured almost full methane conversion, moderate byproduct formation, and high hydrogen yield. A reaction flow analysis of the gas-phase kinetics revealed acetylene, ethylene, and benzene as the main intermediate products and precursors of carbon formation.
Identifiants
pubmed: 36413742
doi: 10.1002/cssc.202201720
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201720Subventions
Organisme : German Federal Ministry of Education and Research
ID : FKZ 03SF0571B
Informations de copyright
© 2022 The Authors. ChemSusChem published by Wiley-VCH GmbH.
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