Phase Transitions and Physical Properties of the Mixed Valence Iron Phosphate Fe

Fe3(PO3OH)4(H2O)4 iron phosphate crystal structures density functional theory mixed valence neutron powder diffraction single crystal x-ray diffraction structural and magnetic phase transitions synthesis

Journal

Materials (Basel, Switzerland)
ISSN: 1996-1944
Titre abrégé: Materials (Basel)
Pays: Switzerland
ID NLM: 101555929

Informations de publication

Date de publication:
15 Nov 2022
Historique:
received: 04 10 2022
revised: 03 11 2022
accepted: 10 11 2022
entrez: 26 11 2022
pubmed: 27 11 2022
medline: 27 11 2022
Statut: epublish

Résumé

Iron phosphate materials have attracted a lot of attention due to their potential as cathode materials for lithium-ion rechargeable batteries. It has been shown that lithium insertion or extraction depends on the Fe mixed valence and reduction or oxidation of the Fe ions' valences. In this paper, we report a new synthesis method for the Fe

Identifiants

pubmed: 36431543
pii: ma15228059
doi: 10.3390/ma15228059
pmc: PMC9696478
pii:
doi:

Types de publication

Journal Article

Langues

eng

Subventions

Organisme : Romanian Ministry of Education and Research, CNCS - UEFISCDI
ID : PN-III-P1-1.1-TE-2019-1767

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Auteurs

Maria Poienar (M)

National Institute for Research and Development in Electrochemistry and Condensed Matter, Str. Dr. Aurel Păunescu Podeanu Nr. 144, 300569 Timisoara, Romania.
MANSiD Research Center and Faculty of Forestry, Stefan Cel Mare University, 720229 Suceava, Romania.

Matthias Josef Gutmann (MJ)

Rutherford Appleton Laboratory, ISIS Facility, Chilton Didcot, Oxfordshire OX11 0QX, UK.

Gheorghe Lucian Pascut (GL)

MANSiD Research Center and Faculty of Forestry, Stefan Cel Mare University, 720229 Suceava, Romania.

Václav Petříček (V)

Institute of Physics, Academy of Sciences of the Czech Republic, 182 21 Prague 8, Czech Republic.

Gavin Stenning (G)

Rutherford Appleton Laboratory, ISIS Facility, Chilton Didcot, Oxfordshire OX11 0QX, UK.

Paulina Vlazan (P)

National Institute for Research and Development in Electrochemistry and Condensed Matter, Str. Dr. Aurel Păunescu Podeanu Nr. 144, 300569 Timisoara, Romania.

Paula Sfirloaga (P)

National Institute for Research and Development in Electrochemistry and Condensed Matter, Str. Dr. Aurel Păunescu Podeanu Nr. 144, 300569 Timisoara, Romania.

Carsten Paulmann (C)

Mineralogisch-Petrographisches Institute, Universität Hamburg, 20146 Hamburg, Germany.

Martin Tolkiehn (M)

Deutsches Elektronensynchrotron DESY, Notkestrasse 85, 22603 Hamburg, Germany.

Pascal Manuel (P)

Rutherford Appleton Laboratory, ISIS Facility, Chilton Didcot, Oxfordshire OX11 0QX, UK.

Philippe Veber (P)

Institut Lumière Matière, Université Claude Bernard Lyon 1, University of Lyon, CNRS, F-69622 Villeurbanne, France.

Classifications MeSH