Trace determination of prohibited acrylamide in cosmetic products by vortex-assisted reversed-phase dispersive liquid-liquid microextraction and liquid chromatography-tandem mass spectrometry.


Journal

Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488

Informations de publication

Date de publication:
04 Jan 2023
Historique:
received: 20 09 2022
revised: 10 11 2022
accepted: 13 11 2022
pubmed: 4 12 2022
medline: 28 12 2022
entrez: 3 12 2022
Statut: ppublish

Résumé

An analytical method for the determination of residual acrylamide in cosmetic products containing potential acrylamide-releasing ingredients is presented. The method is based on vortex-assisted reversed-phase dispersive liquid-liquid microextraction (VA-RP-DLLME) to extract and preconcentrate acrylamide by using water as extraction solvent taking advantage the highly polar behavior of this analyte, followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) for its determination. Under optimized conditions (5 mL toluene as supporting solvent, 50 µL of water as extraction solvent, 1 min for vortex extraction time) the method was properly validated obtaining good analytical features (linearity up to 20 ng mL

Identifiants

pubmed: 36462477
pii: S0021-9673(22)00842-1
doi: 10.1016/j.chroma.2022.463651
pii:
doi:

Substances chimiques

Acrylamide 20R035KLCI
Solvents 0
Water 059QF0KO0R
Cosmetics 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

463651

Informations de copyright

Copyright © 2022 The Author(s). Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Lorenza Schettino (L)

GICAPC Research Group, Department of Analytical Chemistry, University of Valencia, Burjassot, Valencia 46100, Spain.

Alejandro García-Juan (A)

GICAPC Research Group, Department of Analytical Chemistry, University of Valencia, Burjassot, Valencia 46100, Spain.

Laura Fernández-Lozano (L)

GICAPC Research Group, Department of Analytical Chemistry, University of Valencia, Burjassot, Valencia 46100, Spain.

Juan L Benedé (JL)

GICAPC Research Group, Department of Analytical Chemistry, University of Valencia, Burjassot, Valencia 46100, Spain.

Alberto Chisvert (A)

GICAPC Research Group, Department of Analytical Chemistry, University of Valencia, Burjassot, Valencia 46100, Spain. Electronic address: alberto.chisvert@uv.es.

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Classifications MeSH