Efficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations.
Carbonylation
Olefins
Palladium
Plasticizers
Sustainability
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 Feb 2023
01 Feb 2023
Historique:
received:
06
10
2022
pubmed:
6
12
2022
medline:
6
12
2022
entrez:
5
12
2022
Statut:
ppublish
Résumé
Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the "built-in-base" ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (T
Identifiants
pubmed: 36468459
doi: 10.1002/anie.202214706
pmc: PMC10107635
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202214706Subventions
Organisme : Research Foundation Flanders
ID : BioFact 30902231
Organisme : Special research fund (iBOF)
ID : Next-Bioref
Organisme : Francqui foundation
ID : Collen-Francqui research professor
Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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