A Reactive Molecular Dynamics Study of Chlorinated Organic Compounds. Part II: A ChemTraYzer Study of Chlorinated Dibenzofuran Formation and Decomposition Processes.

ChemTraYzer Chlorinated organic compounds Dibenzofurans ParAMS Reactive force fields Self-learning transition-state search

Journal

Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN: 1439-7641
Titre abrégé: Chemphyschem
Pays: Germany
ID NLM: 100954211

Informations de publication

Date de publication:
03 Apr 2023
Historique:
revised: 09 12 2022
received: 18 10 2022
medline: 14 12 2022
pubmed: 14 12 2022
entrez: 13 12 2022
Statut: ppublish

Résumé

In our two-paper series, we first present the development of ReaxFF CHOCl parameters using the recently published ParAMS parametrization tool. In this second part, we update the reactive Molecular Dynamics - Quantum Mechanics coupling scheme ChemTraYzer and combine it with our new ReaxFF parameters from Part I to study formation and decomposition processes of chlorinated dibenzofurans. We introduce a self-learning method for recovering failed transition-state searches that improves the overall ChemTraYzer transition-state search success rate by 10 percentage points to a total of 48 %. With ChemTraYzer, we automatically find and quantify more than 500 reactions using transition state theory and DFT. Among the discovered chlorinated dibenzofuran reactions are numerous reactions that are new to the literature. In three case studies, we discuss the set of reactions that are most relevant to the dibenzofuran literature: (i) bimolecular reactions of the chlorinated-dibenzofuran precursors phenoxy radical and 1,3,5-trichlorobenzene, (ii) dibenzofuran chlorination and pyrolysis, and (iii) oxidation of chlorinated dibenzofurans.

Identifiants

pubmed: 36511423
doi: 10.1002/cphc.202200783
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202200783

Subventions

Organisme : German Federal Ministry of Education and Research (BMBF)
ID : 03EW0009 C
Organisme : European Union's Horizon 2020
ID : 814143
Organisme : Research Board of Ghent University (BOF)
Organisme : RWTH Aachen University
ID : rwth0631

Informations de copyright

© 2022 The Authors. ChemPhysChem published by Wiley-VCH GmbH.

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Auteurs

Lukas Krep (L)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Felix Schmalz (F)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Florian Solbach (F)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Leonid Komissarov (L)

Center for Molecular Modeling (CMM), Ghent University, Technologiepark-Zwijnaarde 46, B-9052, Ghent, Belgium.

Thomas Nevolianis (T)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Wassja A Kopp (WA)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Toon Verstraelen (T)

Center for Molecular Modeling (CMM), Ghent University, Technologiepark-Zwijnaarde 46, B-9052, Ghent, Belgium.

Kai Leonhard (K)

Institute of Technical Thermodynamics, RWTH Aachen University, North Rhine-Westphalia, 52062, Aachen, Germany.

Classifications MeSH