Thermomechanical Properties and Biodegradation Behavior of Itaconic Anhydride-Grafted PLA/Pecan Nutshell Biocomposites.

PLA grafting ball milling biocomposites biodegradation itaconic anhydride (IA) pecan nutshell (PNS) polylactic acid (PLA) soil burial thermal annealing

Journal

Polymers
ISSN: 2073-4360
Titre abrégé: Polymers (Basel)
Pays: Switzerland
ID NLM: 101545357

Informations de publication

Date de publication:
17 Dec 2022
Historique:
received: 17 11 2022
revised: 07 12 2022
accepted: 10 12 2022
entrez: 23 12 2022
pubmed: 24 12 2022
medline: 24 12 2022
Statut: epublish

Résumé

The use of lignocellulose-rich biowaste as reinforcing filler in biodegradable polymers represents a sustainable option to obtain cost-effective bio-based materials to be used for several applications. In addition, the scarce polymer-biofiller interaction can be improved by reactive functionalization of the matrix. However, the obtained biocomposites might show high thermal deformability and possibly a slow biodegradation rate. In this work, polylactic acid (PLA) was first chemically modified with itaconic anhydride, and then biocomposites containing 50 wt.% of pecan (

Identifiants

pubmed: 36559900
pii: polym14245532
doi: 10.3390/polym14245532
pmc: PMC9785769
pii:
doi:

Types de publication

Journal Article

Langues

eng

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Auteurs

Sarai Agustin-Salazar (S)

Institute for Polymers, Composites and Biomaterials (IPCB-CNR), Via Campi Flegrei 34, 80078 Pozzuoli, Italy.
Department of Chemical and Metallurgical Engineering (DIQyM), University of Sonora, Building 5B, Del Conocimiento, Centro, Hermosillo C.P. 83000, Sonora, Mexico.

Marco Ricciulli (M)

Department of Chemical, Materials and Production Engineering (DICMAPI), University of Naples Federico II, Piazzale Tecchio 80, 80125 Naples, Italy.

Veronica Ambrogi (V)

Institute for Polymers, Composites and Biomaterials (IPCB-CNR), Via Campi Flegrei 34, 80078 Pozzuoli, Italy.
Department of Chemical, Materials and Production Engineering (DICMAPI), University of Naples Federico II, Piazzale Tecchio 80, 80125 Naples, Italy.

Pierfrancesco Cerruti (P)

Institute for Polymers, Composites and Biomaterials (IPCB-CNR), Via Gaetano Previati, 1/E, 23900 Lecco, Italy.

Gennaro Scarinzi (G)

Institute for Polymers, Composites and Biomaterials (IPCB-CNR), Via Campi Flegrei 34, 80078 Pozzuoli, Italy.

Classifications MeSH