Binding Energy and Diffusion Barrier of Formic Acid on Pd(111).


Journal

The journal of physical chemistry. A
ISSN: 1520-5215
Titre abrégé: J Phys Chem A
Pays: United States
ID NLM: 9890903

Informations de publication

Date de publication:
12 Jan 2023
Historique:
pubmed: 31 12 2022
medline: 31 12 2022
entrez: 30 12 2022
Statut: ppublish

Résumé

Velocity-resolved kinetics is used to measure the thermal rate of formic acid desorption from Pd(111) between 228 and 273 K for four isotopologues: HCOOH, HCOOD, DCOOH, DCOOD. Upon molecular adsorption, formic acid undergoes decomposition to CO

Identifiants

pubmed: 36583672
doi: 10.1021/acs.jpca.2c07414
pmc: PMC9841570
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

142-152

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Auteurs

Jan Fingerhut (J)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.

Loïc Lecroart (L)

Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.

Dmitriy Borodin (D)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.
Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.

Michael Schwarzer (M)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.

Stefan Hörandl (S)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.

Alexander Kandratsenka (A)

Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.

Daniel J Auerbach (DJ)

Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.

Alec M Wodtke (AM)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.
Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.
International Center for Advanced Studies of Energy Conversion, Georg-August University of Goettingen, Goettingen 37077, Germany.

Theofanis N Kitsopoulos (TN)

Institute for Physical Chemistry, Georg-August University of Goettingen, Goettingen 37077, Germany.
Department of Dynamics at Surfaces, Max Planck Institute for Multidisciplinary Sciences, Goettingen 37077, Germany.
Department of Chemistry, University of Crete, Heraklion 715 00, Greece.
Institute of Electronic Structure and Laser - FORTH, Heraklion 70013, Greece.

Classifications MeSH