MOF/polymer hybrids through
Journal
Materials horizons
ISSN: 2051-6355
Titre abrégé: Mater Horiz
Pays: England
ID NLM: 101623537
Informations de publication
Date de publication:
03 Apr 2023
03 Apr 2023
Historique:
medline:
20
1
2023
pubmed:
20
1
2023
entrez:
19
1
2023
Statut:
epublish
Résumé
We use the free radical polymerization initiator 4,4'-azobis(cyanovaleric acid) coordinated to the open metal sites of metal-organic frameworks (MOFs) to give rise to highly uniform MOF/polymer hybrids. We demonstrate this strategy on two robust zirconium MOFs (NU-1000 and MOF-808), which are the most effective catalysts for degradation of chemical warfare nerve agents. The resulting hybrid materials maintain their hydrolytic catalytic activity and have substantially improved adhesion to polypropylene and activated carbon textile fibers, yielding highly robust MOF/polymer/textile hybrid systems. These composites are suitable for the green production of active protective clothing and filters capable of detoxifying organophosphorus warfare agents.
Identifiants
pubmed: 36655792
doi: 10.1039/d2mh01202b
pmc: PMC10068906
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
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