Temperature and Pressure Dependence of the Reaction between Ethyl Radical and Molecular Oxygen: Experiments and Master Equation Simulations.


Journal

The journal of physical chemistry. A
ISSN: 1520-5215
Titre abrégé: J Phys Chem A
Pays: United States
ID NLM: 9890903

Informations de publication

Date de publication:
09 Feb 2023
Historique:
pubmed: 26 1 2023
medline: 26 1 2023
entrez: 25 1 2023
Statut: ppublish

Résumé

We have used laser-photolysis - photoionization mass-spectrometry to measure the rate coefficient for the reaction between ethyl radical and molecular oxygen as a function of temperature (190-801 K) and pressure (0.2-6 Torr) under pseudo-first-order conditions ([He] ≫ [O

Identifiants

pubmed: 36696672
doi: 10.1021/acs.jpca.2c07780
pmc: PMC9923755
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1302-1313

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Auteurs

Timo T Pekkanen (TT)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland.

Raimo S Timonen (RS)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland.

Elli A Ramu (EA)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland.

György Lendvay (G)

Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Magyar Tudósok krt. 2, Budapest H-1117, Hungary.

Arkke J Eskola (AJ)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland.

Classifications MeSH