Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length.
Journal
Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670
Informations de publication
Date de publication:
05 Aug 2021
05 Aug 2021
Historique:
received:
30
10
2020
accepted:
20
07
2021
entrez:
25
1
2023
pubmed:
5
8
2021
medline:
5
8
2021
Statut:
epublish
Résumé
Controlled formation of desired lanthanide supramolecular complexes is challenging because of the difficulties in predicting coordination geometry, as well as a labile coordination number. Herein, we explore the effect of ionic radii and linker length on supramolecular species formation. A helicate-to-tetrahedron transformation occurred between [Ln
Identifiants
pubmed: 36697590
doi: 10.1038/s42004-021-00553-8
pii: 10.1038/s42004-021-00553-8
pmc: PMC9814731
doi:
Types de publication
Journal Article
Langues
eng
Pagination
116Subventions
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : NSFC, 21875201
Organisme : RCUK | Engineering and Physical Sciences Research Council (EPSRC)
ID : EP/P025013/1
Informations de copyright
© 2021. The Author(s).
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