Site-specific interrogation of an ionic chiral fragment during photolysis using an X-ray free-electron laser.
Journal
Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670
Informations de publication
Date de publication:
12 Aug 2021
12 Aug 2021
Historique:
received:
25
04
2021
accepted:
20
07
2021
entrez:
25
1
2023
pubmed:
12
8
2021
medline:
12
8
2021
Statut:
epublish
Résumé
Short-wavelength free-electron lasers with their ultrashort pulses at high intensities have originated new approaches for tracking molecular dynamics from the vista of specific sites. X-ray pump X-ray probe schemes even allow to address individual atomic constituents with a 'trigger'-event that preludes the subsequent molecular dynamics while being able to selectively probe the evolving structure with a time-delayed second X-ray pulse. Here, we use a linearly polarized X-ray photon to trigger the photolysis of a prototypical chiral molecule, namely trifluoromethyloxirane (C
Identifiants
pubmed: 36697819
doi: 10.1038/s42004-021-00555-6
pii: 10.1038/s42004-021-00555-6
pmc: PMC9814667
doi:
Types de publication
Journal Article
Langues
eng
Pagination
119Subventions
Organisme : Volkswagen Foundation (VolkswagenStiftung)
ID : 93285
Organisme : DOE | SC | Basic Energy Sciences (BES)
ID : DE-AC02-76SF00515
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : 328961117
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : B03/SFB755
Organisme : Bundesministerium für Bildung und Forschung (Federal Ministry of Education and Research)
ID : 05K16RKA
Organisme : Helmholtz Association
ID : Young Investigators Group
Informations de copyright
© 2021. The Author(s).
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