Plasmonic visible-near infrared photothermal activation of olefin metathesis enabling photoresponsive materials.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
Apr 2023
Apr 2023
Historique:
received:
01
12
2021
accepted:
13
12
2022
medline:
27
1
2023
pubmed:
27
1
2023
entrez:
26
1
2023
Statut:
ppublish
Résumé
Light-induced catalysis and thermoplasmonics are promising fields creating many opportunities for innovative research. Recent advances in light-induced olefin metathesis have led to new applications in polymer and material science, but further improvements to reaction scope and efficiency are desired. Herein, we present the activation of latent ruthenium-based olefin metathesis catalysts via the photothermal response of plasmonic gold nanobipyramids. Simple synthetic control over gold nanobipyramid size results in tunable localized surface plasmon resonance bands enabling catalyst initiation with low-energy visible and infrared light. This approach was applied to the ROMP of dicyclopentadiene, affording plasmonic polymer composites with exceptional photoresponsive and mechanical properties. Moreover, this method of catalyst activation was proven to be remarkably more efficient than activation through conventional heating in all the metathesis processes tested. This study paves the way for providing a wide range of photoinduced olefin metathesis processes in particular and photoinduced latent organic reactions in general by direct photothermal activation of thermally latent catalysts.
Identifiants
pubmed: 36702882
doi: 10.1038/s41557-022-01124-7
pii: 10.1038/s41557-022-01124-7
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
475-482Subventions
Organisme : Israel Science Foundation (ISF)
ID : 2491/20
Organisme : Israel Science Foundation (ISF)
ID : 506/18
Informations de copyright
© 2023. The Author(s), under exclusive licence to Springer Nature Limited.
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