Boranes Paving the Way to Anionic Cyclic (Alkyl)(amino)carbenes (Ani-cAACs).
N-heterocyclic carbene
anionic carbene
borane
cyclic alkyl(amino)carbene (cAAC)
perfluoroalkyl
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
17 Apr 2023
17 Apr 2023
Historique:
received:
03
01
2023
medline:
29
1
2023
pubmed:
29
1
2023
entrez:
28
1
2023
Statut:
ppublish
Résumé
First examples of anionic cyclic (alkyl)(amino)carbenes (Ani-cAACs) that contain borane substituents have been synthesized. The nature of the borane substituents allows a modulation of the σ-donor or π-acceptor abilities compared to their neutral analogues. A B(CN)
Identifiants
pubmed: 36708215
doi: 10.1002/anie.202300056
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202300056Subventions
Organisme : Studienstiftung des Deutschen Volkes
Organisme : Julius-Maximilians-Universität Würzburg
Informations de copyright
© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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Deposition Numbers 2233226 (1), 2233227 (2⋅CH2Cl2), 2233228 (4), 2233229 (2∞[Li5⋅CH2Cl2], 2233230 ([Li6⋅THF]2), 2233232 ([PPh4]7), 2233231 (Li8 ⋅ (THF)2), 2233233 (9 ⋅ (C6H6)0.25) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service www.ccdc.cam.ac.uk/ structures.