Strong-Proton-Adsorption Co-Based Electrocatalysts Achieve Active and Stable Neutral Seawater Splitting.

cobalt oxide neutral seawater splitting oxygen evolution reaction strong-proton-adsorption effect

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Apr 2023
Historique:
revised: 21 01 2023
received: 31 10 2022
medline: 1 2 2023
pubmed: 1 2 2023
entrez: 31 1 2023
Statut: ppublish

Résumé

Direct electrolysis of pH-neutral seawater to generate hydrogen is an attractive approach for storing renewable energy. However, due to the anodic competition between the chlorine evolution and the oxygen evolution reaction (OER), direct seawater splitting suffers from a low current density and limited operating stability. Exploration of catalysts enabling an OER overpotential below the hypochlorite formation overpotential (≈490 mV) is critical to suppress the chloride evolution and facilitate seawater splitting. Here, a proton-adsorption-promoting strategy to increase the OER rate is reported, resulting in a promoted and more stable neutral seawater splitting. The best catalysts herein are strong-proton-adsorption (SPA) materials such as palladium-doped cobalt oxide (Co

Identifiants

pubmed: 36719140
doi: 10.1002/adma.202210057
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2210057

Subventions

Organisme : Natural Gas Innovation Fund, the Natural Sciences and Engineering Research Council
Organisme : Qatar National Research Fund under its National Priorities Research Program
ID : NPRP12S-0131-190024
Organisme : Ontario Research Fund - Research Excellence program
Organisme : Canada Foundation for Innovation, the Government of Ontario
Organisme : Ontario Research Fund Research Excellence Program
Organisme : National Natural Science Foundation of China
ID : 51771132
Organisme : NSTC
ID : NSTC111-2628-M-A49-007-

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Ning Wang (N)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.
School of Materials Science and Engineering and Key Laboratory of Efficient Utilization of Low and Medium Grade Energy, Ministry of Education, Tianjin University, Tianjin, 300350, P. R. China.

Pengfei Ou (P)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Sung-Fu Hung (SF)

Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 300, Taiwan.

Jianan Erick Huang (JE)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Adnan Ozden (A)

Department of Mechanical and Industrial Engineering, University of Toronto, 5 King's College Road, Toronto, Ontario, M5S 3G8, Canada.

Jehad Abed (J)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Ivan Grigioni (I)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Clark Chen (C)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Rui Kai Miao (RK)

Department of Mechanical and Industrial Engineering, University of Toronto, 5 King's College Road, Toronto, Ontario, M5S 3G8, Canada.

Yu Yan (Y)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Jinqiang Zhang (J)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Ziyun Wang (Z)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Roham Dorakhan (R)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Ahmed Badreldin (A)

Chemical Engineering Program, Texas A&M University at Qatar, Doha, 23874, Qatar.

Ahmed Abdel-Wahab (A)

Chemical Engineering Program, Texas A&M University at Qatar, Doha, 23874, Qatar.

David Sinton (D)

Department of Mechanical and Industrial Engineering, University of Toronto, 5 King's College Road, Toronto, Ontario, M5S 3G8, Canada.

Yongchang Liu (Y)

School of Materials Science and Engineering and Key Laboratory of Efficient Utilization of Low and Medium Grade Energy, Ministry of Education, Tianjin University, Tianjin, 300350, P. R. China.
State Key Lab of Hydraulic Engineering Simulation and Safety, Tianjin University, Tianjin, 300350, P.R. China.

Hongyan Liang (H)

School of Materials Science and Engineering and Key Laboratory of Efficient Utilization of Low and Medium Grade Energy, Ministry of Education, Tianjin University, Tianjin, 300350, P. R. China.

Edward H Sargent (EH)

Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario, M5S 1A4, Canada.

Classifications MeSH