Pyrite contact twins.

contact twin iron cross twin merohedry morphology pyrite reticular merohedry spinel twin

Journal

Acta crystallographica Section B, Structural science, crystal engineering and materials
ISSN: 2052-5206
Titre abrégé: Acta Crystallogr B Struct Sci Cryst Eng Mater
Pays: England
ID NLM: 101609037

Informations de publication

Date de publication:
01 Feb 2023
Historique:
received: 10 07 2022
accepted: 06 12 2022
entrez: 7 2 2023
pubmed: 8 2 2023
medline: 8 2 2023
Statut: ppublish

Résumé

Two examples of contact twins in pyrite from Peru are described. The first one, from Pasto Bueno ore deposit, shows the pyritohedron {120} as principal form, accompanied by the {111} octahedron and {100} cube as secondary forms, giving a lenticular aspect. (111) is the composition plane, and the twin operation is any one of the three binary axes ⟨110⟩ within this plane. The second one (unknown ore deposit) presents two forms, the octahedron {111} and the pyritohedron {120}; the two crystals in the twin are elongated along [101] and [011], respectively, producing a V profile. It is a reflection twin where the twin plane (110) coincides with the composition plane. These twins are by merohedry. Another contact twin is known in the literature, reported by Gaubert [Bull. Soc. Fr. Minéral. Cristallogr. (1928), 51, 211-212] who described it as a spinel twin, i.e. a reflection twin with twin and composition plane (111); here it is shown that it is actually a rotation twin in which the twin operation is a 180° rotation about any of the three equivalent directions ⟨211⟩, contained in the (111) composition plane. The occurrence of these twins as well as the doubtfulness of the spinel twin in pyrite shows a direct relationship with the structural interpretation based on the pseudo-symmetry of the crystallographic orbits.

Identifiants

pubmed: 36748896
pii: S2052520622011714
doi: 10.1107/S2052520622011714
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

32-45

Auteurs

Yves Moëlo (Y)

Nantes University, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.

Massimo Nespolo (M)

Université de Lorraine, CRNS, CRM2, Nancy, France.

François Farges (F)

Muséum National d'Histoire Naturelle (MNHN), CNRS, IMPMC, Paris, France.

Classifications MeSH