Emergence of chaos in a compartmentalized catalytic reaction nanosystem.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
10 Feb 2023
Historique:
received: 25 07 2022
accepted: 01 02 2023
entrez: 9 2 2023
pubmed: 10 2 2023
medline: 10 2 2023
Statut: epublish

Résumé

In compartmentalized systems, chemical reactions may proceed in differing ways even in adjacent compartments. In compartmentalized nanosystems, the reaction behaviour may deviate from that observed on the macro- or mesoscale. In situ studies of processes in such nanosystems meet severe experimental challenges, often leaving the field to theoretical simulations. Here, a rhodium nanocrystal surface consisting of different nm-sized nanofacets is used as a model of a compartmentalized reaction nanosystem. Using field emission microscopy, different reaction modes are observed, including a transition to spatio-temporal chaos. The transitions between different modes are caused by variations of the hydrogen pressure modifying the strength of diffusive coupling between individual nanofacets. Microkinetic simulations, performed for a network of 52 coupled oscillators, reveal the origins of the different reaction modes. Since diffusive coupling is characteristic for many living and non-living compartmentalized systems, the current findings may be relevant for a wide class of reaction systems.

Identifiants

pubmed: 36759520
doi: 10.1038/s41467-023-36434-y
pii: 10.1038/s41467-023-36434-y
pmc: PMC9911747
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

736

Subventions

Organisme : Austrian Science Fund (Fonds zur Förderung der Wissenschaftlichen Forschung)
ID : P 32772-N
Organisme : Japan Society for the Promotion of Science London (JSPS London)
ID : JP 20K19882

Informations de copyright

© 2023. The Author(s).

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Auteurs

Maximilian Raab (M)

Institute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060, Vienna, Austria.

Johannes Zeininger (J)

Institute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060, Vienna, Austria.

Yuri Suchorski (Y)

Institute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060, Vienna, Austria.

Keita Tokuda (K)

Department of Computer Science, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki, 305-8577, Japan.

Günther Rupprechter (G)

Institute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060, Vienna, Austria. guenther.rupprechter@tuwien.ac.at.

Classifications MeSH