Emergence of chaos in a compartmentalized catalytic reaction nanosystem.
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
10 Feb 2023
10 Feb 2023
Historique:
received:
25
07
2022
accepted:
01
02
2023
entrez:
9
2
2023
pubmed:
10
2
2023
medline:
10
2
2023
Statut:
epublish
Résumé
In compartmentalized systems, chemical reactions may proceed in differing ways even in adjacent compartments. In compartmentalized nanosystems, the reaction behaviour may deviate from that observed on the macro- or mesoscale. In situ studies of processes in such nanosystems meet severe experimental challenges, often leaving the field to theoretical simulations. Here, a rhodium nanocrystal surface consisting of different nm-sized nanofacets is used as a model of a compartmentalized reaction nanosystem. Using field emission microscopy, different reaction modes are observed, including a transition to spatio-temporal chaos. The transitions between different modes are caused by variations of the hydrogen pressure modifying the strength of diffusive coupling between individual nanofacets. Microkinetic simulations, performed for a network of 52 coupled oscillators, reveal the origins of the different reaction modes. Since diffusive coupling is characteristic for many living and non-living compartmentalized systems, the current findings may be relevant for a wide class of reaction systems.
Identifiants
pubmed: 36759520
doi: 10.1038/s41467-023-36434-y
pii: 10.1038/s41467-023-36434-y
pmc: PMC9911747
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
736Subventions
Organisme : Austrian Science Fund (Fonds zur Förderung der Wissenschaftlichen Forschung)
ID : P 32772-N
Organisme : Japan Society for the Promotion of Science London (JSPS London)
ID : JP 20K19882
Informations de copyright
© 2023. The Author(s).
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