Self-Assembly of a Purely Organic Bowl in Water via Acylhydrazone Formation.
dynamic covalent chemistry
self-assembly
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
18 Jan 2023
18 Jan 2023
Historique:
received:
07
12
2022
revised:
05
01
2023
accepted:
11
01
2023
entrez:
11
2
2023
pubmed:
12
2
2023
medline:
12
2
2023
Statut:
epublish
Résumé
A bowl-shaped molecule can be self-assembled by condensing a triscationic hexaaldehyde compound and three equiv. of a dihydrazide linkers in pure water. The molecular bowl is thus composed of a triscationic π-electron deficient platform, as well as a hexagonal rim that contains six acylhydrazone functions. When the counteranions are chloride, the solid-state structure reveals that this molecular bowl undergoes dimerization via N-H···Cl hydrogen bonds, forming a cage-like dimer with a huge inner cavity. This molecular bowl can employ its cavity to accommodate a hydrophobic guest, namely 1-adamantanecarboxylic acid in aqueous media.
Identifiants
pubmed: 36770651
pii: molecules28030976
doi: 10.3390/molecules28030976
pmc: PMC9921396
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
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