Molecular Alignment-Induced Chemically Patchy Uniaxial Nanoparticles and Their Applications in Anti-Counterfeiting and Self-Assembled Superstructures.

Anisotropy Anti-Counterfeiting Liquid Crystals Patchy Nanoparticles Self-Assembly

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
11 Apr 2023
Historique:
received: 13 12 2022
medline: 17 2 2023
pubmed: 17 2 2023
entrez: 16 2 2023
Statut: ppublish

Résumé

We report an unusual strategy for synthesizing patchy nanoparticles (NPs) by controlling the orientation of the molecules that form the NPs. This is realized by synchronous polymerization and crystallization of liquid crystal (LC) monomers during scalable precipitation polymerization. The resulting NPs are cylinders with highly uniform shapes and have only a single LC domain. The patchy properties originate from the discrepancy of surface chemical compositions on flat and side surfaces and can be switched on and off by solvent. Extra colloidal blocks can be grown onto the patches, resulting in highly uniform triblock patchy dumbbells, which have integrated optical properties, and as demonstrated, show triple-mode optical authentication in anti-counterfeiting labels or patterns. We also demonstrate that the triblock patchy cylinders are attractive building blocks for long LC rods or porous colloidal materials through polymerization-induced self-assembly.

Identifiants

pubmed: 36797514
doi: 10.1002/anie.202218399
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202218399

Subventions

Organisme : Ministry of Science and Technology of the People´s Republic of China
ID : 2021YFA0716700
Organisme : National Natural Science Foundation of China
ID : 22172175

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Xiao Wang (X)

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China.
University of the Chinese Academy of Sciences, 100149, Beijing, China.

Bing Liu (B)

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China.
University of the Chinese Academy of Sciences, 100149, Beijing, China.

Classifications MeSH