Chalcogen Bonding Catalysis of the Cloke-Wilson Rearrangement.

Cloke-Wilson rearrangement Se⋅⋅⋅O bonding chalcogen bonding cyclopropanes supramolecular catalysis

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
08 May 2023
Historique:
received: 07 12 2022
medline: 18 2 2023
pubmed: 18 2 2023
entrez: 17 2 2023
Statut: ppublish

Résumé

The Cloke-Wilson rearrangement is an important method to construct heterocycles which was conventionally facilitated by strong Lewis acids, Brønsted acids and Lewis bases. A weak interaction catalysis approach to the Cloke-Wilson rearrangement remains a challenging topic and yet no example is reported. Herein, a chalcogen bonding catalysis method to achieve the Cloke-Wilson rearrangement is described that involves activation of carbonyl cyclopropanes by double Se⋅⋅⋅O interactions. This chalcogen bonding catalysis approach afforded a wide range of dihydrofurans with good yields, thus establishing an alternative strategy to catalyze the Cloke-Wilson rearrangement.

Identifiants

pubmed: 36799517
doi: 10.1002/chem.202203822
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202203822

Subventions

Organisme : National Natural Science Foundation of China
ID : 22022105, 21971147, 21772113

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Xinglong Yuan (X)

School of Chemistry and Chemical Engineering Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, P. R. China.

Lintao Bao (L)

School of Chemistry and Chemical Engineering Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, P. R. China.

Zhiguo Zhao (Z)

School of Chemistry and Chemical Engineering Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, P. R. China.

Yao Wang (Y)

School of Chemistry and Chemical Engineering Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, P. R. China.

Classifications MeSH