Tuning nonequilibrium phase transitions with inertia.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
21 Feb 2023
Historique:
entrez: 22 2 2023
pubmed: 23 2 2023
medline: 23 2 2023
Statut: ppublish

Résumé

In striking contrast to equilibrium systems, inertia can profoundly alter the structure of active systems. Here, we demonstrate that driven systems can exhibit effective equilibrium-like states with increasing particle inertia, despite rigorously violating the fluctuation-dissipation theorem. Increasing inertia progressively eliminates motility-induced phase separation and restores equilibrium crystallization for active Brownian spheres. This effect appears to be general for a wide class of active systems, including those driven by deterministic time-dependent external fields, whose nonequilibrium patterns ultimately disappear with increasing inertia. The path to this effective equilibrium limit can be complex, with finite inertia sometimes acting to accentuate nonequilibrium transitions. The restoration of near equilibrium statistics can be understood through the conversion of active momentum sources to passive-like stresses. Unlike truly equilibrium systems, the effective temperature is now density dependent, the only remnant of the nonequilibrium dynamics. This density-dependent temperature can in principle introduce departures from equilibrium expectations, particularly in response to strong gradients. Our results provide additional insight into the effective temperature ansatz while revealing a mechanism to tune nonequilibrium phase transitions.

Identifiants

pubmed: 36813709
doi: 10.1063/5.0138256
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

074904

Auteurs

Ahmad K Omar (AK)

Department of Materials Science and Engineering, University of California, Berkeley, California 94720, USA.

Katherine Klymko (K)

NERSC, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.

Trevor GrandPre (T)

Department of Physics, University of California, Berkeley, California 94720, USA.

Phillip L Geissler (PL)

Department of Chemistry, University of California, Berkeley, California 94720, USA.

John F Brady (JF)

Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Classifications MeSH