Water Increases the Faradaic Selectivity of Li-Mediated Nitrogen Reduction.


Journal

ACS energy letters
ISSN: 2380-8195
Titre abrégé: ACS Energy Lett
Pays: United States
ID NLM: 101697523

Informations de publication

Date de publication:
10 Feb 2023
Historique:
received: 08 12 2022
accepted: 27 01 2023
entrez: 23 2 2023
pubmed: 24 2 2023
medline: 24 2 2023
Statut: epublish

Résumé

The lithium-mediated system catalyzes nitrogen to ammonia under ambient conditions. Herein we discover that trace amount of water as an electrolyte additive-in contrast to prior reports from the literature-can effect a dramatic improvement in the Faradaic selectivity of N

Identifiants

pubmed: 36816776
doi: 10.1021/acsenergylett.2c02792
pmc: PMC9926485
doi:

Types de publication

Journal Article

Langues

eng

Pagination

1230-1235

Informations de copyright

© 2023 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

Références

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Auteurs

Matthew Spry (M)

Department of Materials, Imperial College London, Prince Consort Road, South Kensington, London, SW7 2AZ, U.K.

Olivia Westhead (O)

Department of Materials, Imperial College London, Prince Consort Road, South Kensington, London, SW7 2AZ, U.K.

Romain Tort (R)

Department of Chemical Engineering, Imperial College London, Imperial College Rd, South Kensington, London, SW7 2AZ, U.K.

Benjamin Moss (B)

Department of Materials, Imperial College London, Prince Consort Road, South Kensington, London, SW7 2AZ, U.K.

Yu Katayama (Y)

SANKEN (Institute of Scientific and Industrial Research), Osaka University, Mihogaoka, Ibaraki, Osaka 567-0047, Japan.

Maria-Magdalena Titirici (MM)

Department of Chemical Engineering, Imperial College London, Imperial College Rd, South Kensington, London, SW7 2AZ, U.K.

Ifan E L Stephens (IEL)

Department of Materials, Imperial College London, Prince Consort Road, South Kensington, London, SW7 2AZ, U.K.

Alexander Bagger (A)

Department of Chemical Engineering, Imperial College London, Imperial College Rd, South Kensington, London, SW7 2AZ, U.K.

Classifications MeSH