Friedel-Crafts acylation of benzene derivatives in tunable aryl alkyl ionic liquids (TAAILs).
Friedel–Crafts acylation
TAAILs
homogeneous catalysis
ionic liquids
iron catalysis
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2023
2023
Historique:
received:
06
11
2022
accepted:
30
01
2023
entrez:
3
3
2023
pubmed:
4
3
2023
medline:
4
3
2023
Statut:
epublish
Résumé
An iron(III) chloride hexahydrate-catalyzed Friedel-Crafts acylation of benzene derivatives in tunable aryl alkyl ionic liquids (TAAILs) has been developed. Through optimization of the metal salt, reaction conditions and ionic liquids, we were able to design a robust catalyst system that tolerates different electron-rich substrates under ambient atmosphere and allows for a multigram scale.
Identifiants
pubmed: 36865025
doi: 10.3762/bjoc.19.20
pmc: PMC9972882
doi:
Types de publication
Journal Article
Langues
eng
Pagination
212-216Informations de copyright
Copyright © 2023, Lerch et al.
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