Engineering Flexible Metal-Phenolic Networks with Guest Responsiveness via Intermolecular Interactions.
Competitive Coordination Assembly
Guest-Responsive Materials
Metal-Organic Frameworks
Microcapsules
Supramolecular Chemistry
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
24 Apr 2023
24 Apr 2023
Historique:
received:
16
02
2023
medline:
6
3
2023
pubmed:
6
3
2023
entrez:
5
3
2023
Statut:
ppublish
Résumé
Flexible metal-organic materials are of growing interest owing to their ability to undergo reversible structural transformations under external stimuli. Here, we report flexible metal-phenolic networks (MPNs) featuring stimuli-responsive behavior to diverse solute guests. The competitive coordination of metal ions to phenolic ligands of multiple coordination sites and solute guests (e.g., glucose) primarily determines the responsive behavior of the MPNs, as revealed experimentally and computationally. Glucose molecules can be embedded into the dynamic MPNs upon mixing, leading to the reconfiguration of the metal-organic networks and thus changes in their physicochemical properties for targeting applications. This study expands the library of stimuli-responsive flexible metal-organic materials and the understanding of intermolecular interactions between metal-organic materials and solute guests, which is essential for the rational design of responsive materials for various applications.
Identifiants
pubmed: 36872291
doi: 10.1002/anie.202302448
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202302448Subventions
Organisme : National Health and Medical Research Council
ID : GNT2016732
Organisme : National Natural Science Foundation of China
ID : 51703056
Organisme : Hunan Provincial Science and Technology Department
ID : 2018JJ3028
Organisme : Australian Research Council
ID : DP170100511
Organisme : Australian Research Council
ID : DP190102290
Organisme : National Computational Infrastructure
ID : NCMAS grant e87
Organisme : China Scholarship Council
Organisme : Changsha Science and Technology Bureau
ID : kq2208015
Informations de copyright
© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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