An easy-to-perform evaluation of steric properties of Lewis acids.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
01 Mar 2023
01 Mar 2023
Historique:
received:
03
01
2023
accepted:
04
02
2023
entrez:
6
3
2023
pubmed:
7
3
2023
medline:
7
3
2023
Statut:
epublish
Résumé
Steric and electronic effects play a very important role in chemistry, as these effects influence the shape and reactivity of molecules. Herein, an easy-to-perform approach to assess and quantify steric properties of Lewis acids with differently substituted Lewis acidic centers is reported. This model applies the concept of the percent buried volume (%
Identifiants
pubmed: 36873848
doi: 10.1039/d3sc00037k
pii: d3sc00037k
pmc: PMC9977453
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2275-2288Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
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