A customized strategy to design intercalation-type Li-free cathodes for all-solid-state batteries.
all-solid-state Li-metal batteries
energy density
intercalation-type Li-free cathodes
ligand-field descriptors
p-type alloying strategy
Journal
National science review
ISSN: 2053-714X
Titre abrégé: Natl Sci Rev
Pays: China
ID NLM: 101633095
Informations de publication
Date de publication:
Mar 2023
Mar 2023
Historique:
received:
21
09
2022
revised:
15
12
2022
accepted:
04
01
2023
entrez:
6
3
2023
pubmed:
7
3
2023
medline:
7
3
2023
Statut:
epublish
Résumé
Pairing Li-free transition-metal-based cathodes (MX) with Li-metal anodes is an emerging trend to overcome the energy-density limitation of current rechargeable Li-ion technology. However, the development of practical Li-free MX cathodes is plagued by the existing notion of low voltage due to the long-term overlooked voltage-tuning/phase-stability competition. Here, we propose a p-type alloying strategy involving three voltage/phase-evolution stages, of which each of the varying trends are quantitated by two improved ligand-field descriptors to balance the above contradiction. Following this, an intercalation-type 2H-V
Identifiants
pubmed: 36875788
doi: 10.1093/nsr/nwad010
pii: nwad010
pmc: PMC9976772
doi:
Types de publication
Journal Article
Langues
eng
Pagination
nwad010Informations de copyright
© The Author(s) 2023. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd.
Références
Nat Commun. 2020 Mar 25;11(1):1550
pubmed: 32214093
Nature. 2008 Feb 7;451(7179):652-7
pubmed: 18256660
Sci Data. 2020 May 21;7(1):151
pubmed: 32439922
Phys Rev B Condens Matter. 1996 Oct 15;54(16):11169-11186
pubmed: 9984901
ACS Appl Mater Interfaces. 2018 Mar 28;10(12):10053-10063
pubmed: 29498503
Phys Rev Lett. 2014 Jul 11;113(2):028304
pubmed: 25062244
Science. 1976 Jun 11;192(4244):1126-7
pubmed: 17748676
Adv Mater. 2017 Sep;29(35):
pubmed: 28714200
Nat Commun. 2019 Apr 16;10(1):1764
pubmed: 30992432
Chem Rev. 2017 Aug 9;117(15):10403-10473
pubmed: 28753298
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):364-9
pubmed: 12037357
Phys Rev B Condens Matter. 1992 Sep 15;46(11):6671-6687
pubmed: 10002368
Phys Rev Lett. 2011 Apr 8;106(14):145501
pubmed: 21561201
ACS Nano. 2018 Feb 27;12(2):2035-2047
pubmed: 29425020
J Comput Chem. 2006 Nov 30;27(15):1787-99
pubmed: 16955487
Nat Chem. 2013 Apr;5(4):263-75
pubmed: 23511414
Acc Chem Res. 2013 May 21;46(5):1216-25
pubmed: 22584006
Nature. 2000 Sep 28;407(6803):496-9
pubmed: 11028997
J Am Chem Soc. 2011 Nov 9;133(44):17832-8
pubmed: 21951158
Nature. 2018 Jul;559(7715):556-563
pubmed: 30046074
Small. 2018 Mar;14(9):
pubmed: 29280269
iScience. 2020 Aug 28;23(9):101505
pubmed: 32947125
Chem Rev. 2020 Jul 22;120(14):6820-6877
pubmed: 31763824
Chem Soc Rev. 2021 Nov 29;50(23):13189-13235
pubmed: 34719701