Intramolecular Ynamide-Benzyne (3+2) Cycloadditions.

Benzyne Cycloaddition Heterocycles Ylides Ynamides

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
02 May 2023
Historique:
received: 17 01 2023
medline: 10 3 2023
pubmed: 10 3 2023
entrez: 9 3 2023
Statut: ppublish

Résumé

We report herein intramolecular (3+2) cycloaddition reactions between ynamides as three-atom components and benzyne. In these intramolecular reactions, the two-bond formation is realized by exploiting benzyne precursors that contain a chlorosilyl group as a linking functionality. This method thus highlights the ambivalent character of the intermediate indolium ylide, which exhibits both nucleophilic and electrophilic properties at its C2 atom.

Identifiants

pubmed: 36895082
doi: 10.1002/anie.202300907
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202300907

Subventions

Organisme : Japan Society for the Promotion of Science
ID : 21H02068
Organisme : Japan Society for the Promotion of Science
ID : 21H05211
Organisme : Shionogi
Organisme : Japan Science Society
ID : Sasakawa Scientific Research Grant
Organisme : Japan Science and Technology Agency
ID : the establishment of university fellowships towards the creation of science technology innovation - JPMJFS2123
Organisme : Japan Agency for Medical Research and Development
ID : 22ama121042j0001
Organisme : Japan Agency for Medical Research and Development
ID : 22ama121034j0001

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Tsukasa Tawatari (T)

Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan.

Ritsuki Kato (R)

Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan.

Riku Kudo (R)

Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan.

Kiyosei Takasu (K)

Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan.

Hiroshi Takikawa (H)

Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan.

Classifications MeSH