Spin polarization through axially chiral linkers: Length dependence and correlation with the dissymmetry factor.
CISS
circular dichroism
electron transfer
optical activity
spin
Journal
Chirality
ISSN: 1520-636X
Titre abrégé: Chirality
Pays: United States
ID NLM: 8914261
Informations de publication
Date de publication:
Sep 2023
Sep 2023
Historique:
revised:
17
02
2023
received:
24
01
2023
accepted:
24
02
2023
medline:
11
3
2023
pubmed:
11
3
2023
entrez:
10
3
2023
Statut:
ppublish
Résumé
The chiral-induced spin selectivity (CISS) effect relates to the spin-selective electron transport through chiral molecules; therefore, the chiral molecules act as spin filters. In past studies, correlation was found between the magnitude of the spin filtering and the intensity of the circular dichroism (CD) spectrum (the first Compton peak) of the molecules. Since the intensity of the CD peak relates to both the magnitude of the electric and magnetic dipole transitions, it was not clear which of these properties correlate with the CISS effect. This work aims at addressing this question. By studying the spin-dependent conduction and the CD spectra of the thiol-functionalized enantiopure binaphthalene (BINAP) and ternaphthalene (TERNAP), we found that both BINAP and TERNAP exhibit a similar spin polarization of 50%, despite the first Compton peak in TERNAP being almost twice as intense as the peak in BINAP. These results can be explained by the similar values of their anisotropy (or dissymmetry) factor, g
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
562-568Subventions
Organisme : Jay and Sharon Levy, the Sassoon and Marjorie Peress Philanthropic Fund, and the Estate of Hermine Miller
Organisme : US Department of Energy (Office of Science, Office of Basic Energy Sciences and Energy Efficiency and Renewable Energy, Solar Energy Technology Program)
ID : ER46430
Organisme : European Union's Horizon 2020
ID : 850836
Informations de copyright
© 2023 The Authors. Chirality published by Wiley Periodicals LLC.
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